Synthesis of C1 Bridge-containing Metallocene Catalysts and Their Catalytic Activities for Olefin Polymerization

Abstract

Abstract: The synthesis and characterization of metallocene complexes which can be used as catalysts in the presence of MAOfor olefin polymerization were discussed in the present paper. The metallocene complexes have been characterized by IR, ¹H NMR, EI-MSspectra and element analyses. The catalytic features of olefin polymerization were studied under different conditions. Metallocenes in which metals is Ti had no activity for ethylene polymerization. Polymers with different features can be obtained by using different catalysts.

Key words: Metallocene, Olefin polymerization, Catalyst

CLC Number:

O614.4

TrendMD:

ZHOU Guang-Yuan, JIN Guo-Xin, HUANG Bao-Tong . Synthesis of C₁ Bridge-containing Metallocene Catalysts and Their Catalytic Activities for Olefin Polymerization[J]. Chem. J. Chinese Universities, 2000, 21(9): 1489.

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Synthesis of C₁ Bridge-containing Metallocene Catalysts and Their Catalytic Activities for Olefin Polymerization

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