Nonaqueous Synthesis and Characterization of a Zincophosphate with 12-Membered Ring Channel Open Framework

Chem. J. Chinese Universities ›› 2000, Vol. 21 ›› Issue (4): 509.

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Nonaqueous Synthesis and Characterization of a Zincophosphate with 12-Membered Ring Channel Open Framework

XU Jia-Ning¹, YUAN Hong-Ming¹, MAO You-Gang², SHI Su-Hua¹, LEE Young-K.³, CHANG Tae-Sun³, SONG Tian-You¹, FENG Shou-Hua¹, XU Ru-Ren¹

1. Departmentof Chemistry, Key Laboratory of Inorganic Synthesisand Preparative Chemistry;
2. Key Laboratoryof Supermolecular Structureand Spectra, Jilin University, Changchun, China, 130023;
3. Chemical Technology Division, Korea Research Instituteof Chemical Technology, Taejon 305-600, Korea

Received:1999-06-23 Online:2000-04-24 Published:2000-04-24

Abstract

Abstract: Single crystal of Zn₂(HPO₄)₃·H₃NCH₂CH₂NH₃ was synthesized from nonaqueous system and its crystal structure was determined using single crystal X-ray diffraction. The crystal structure was solved by direct method and refined by full-matrix least-square method and the crystal is triclinic, space group P1 with a =0.8215(3) nm, b =0.8557(3) nm, c =0.9760(3) nm, α =93.8(3)°, β =95.38(3)°, γ =109.75(3)°, V =0.6394 nm³, Z =2, D_c=2.50 g·cm^-3 , μ =43.0 cm^-1 , R =0.031, R_w=0.040. The framework is built up from ZnO₄ and HPO₄ tetrahedra, forming a three dimensional network, and the linkage of Zn and Ptetrahedra displays a strict alternation of zinc and phosphorus. The open framework contains 8-membered ring channels and 12-membered ring channels. The results of XRD, IRand DTA-TGfor the compound are given.

Key words: Zincophosphate, Nonaqueous system, Crystal structure

CLC Number:

O614

TrendMD:

XU Jia-Ning, YUAN Hong-Ming, MAO You-Gang, SHI Su-Hua, LEE Young-K., CHANG Tae-Sun, SONG Tian-You, FENG Shou-Hua, XU Ru-Ren . Nonaqueous Synthesis and Characterization of a Zincophosphate with 12-Membered Ring Channel Open Framework[J]. Chem. J. Chinese Universities, 2000, 21(4): 509.

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Nonaqueous Synthesis and Characterization of a Zincophosphate with 12-Membered Ring Channel Open Framework

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