The Synthesis of Phenyl-capped Trianiline and Teraaniline by A Modified-pseudo-high Dilution Technique and Their UV-Vis Spectral Studies

Chem. J. Chinese Universities ›› 2000, Vol. 21 ›› Issue (2): 315.

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The Synthesis of Phenyl-capped Trianiline and Teraaniline by A Modified-pseudo-high Dilution Technique and Their UV-Vis Spectral Studies

GAO Jun-Bo¹, LI Ke¹, SUN Hui¹, YU You-Hai¹, WANG Ce WU Zhong-Wen¹, ZHANG Wan-Jin¹, JI Yi-Ping¹

1. Department of Chemistry, Jilin University, Changchun 130023, China;
2. Changchun Instituteof Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Received:1999-06-30 Online:2000-02-24 Published:2000-02-24

Abstract

Abstract: Phenylcapped trianiline and tetraaniline in the leucoemeraldine oxidation state were synthesized through a modified-pseudo-high-dilution technique. The chemical oxidation process of these compounds were studied by UV-Vi s spectra. It was found that phenyl-capped trianiline in the leucoemeraldine oxidation state was oxidized to its EBform and then decomposed. Phenyl-capped tetraaniline was oxidized to its EBform and then to the pernigraniline oxidation state.

Key words: Polyaniline, Oxidative coupling reaction, Oligomers, UV-V is spectra

CLC Number:

O631

TrendMD:

GAO Jun-Bo, LI Ke, SUN Hui, YU You-Hai, WANG Ce WU Zhong-Wen, ZHANG Wan-Jin, JI Yi-Ping. The Synthesis of Phenyl-capped Trianiline and Teraaniline by A Modified-pseudo-high Dilution Technique and Their UV-Vis Spectral Studies[J]. Chem. J. Chinese Universities, 2000, 21(2): 315.

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The Synthesis of Phenyl-capped Trianiline and Teraaniline by A Modified-pseudo-high Dilution Technique and Their UV-Vis Spectral Studies

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