Syntheses and Crystal Structures of Transitional Metal Complexes with Polypyridines as Ligands

Abstract

Abstract: The syntheses and crystal structures of transitional metal complexes of three substituted polypyridine ligands[4′-phenyl-2, 2′∶6′, 2″-terpyridine(L1), 4′, 4″-diphenyl-2, 2′∶6′, 2″∶6″, 2-quaterpyridine(L2)and 4′, 4Ê-diphenyl-2, 2′∶6′, 2″∶6″, 2Ê∶6Ê, 2″″-quenquepyridine(L3)] are reported in this work. Comparison of the structures of these complexes shows that the central metal ion has an inducing effect on the formation of the configuration of complexes.

Key words: Polypyridine, Assembly, Inducing effect

CLC Number:

O614

TrendMD:

YIN Ye-Gao, CHEUNG Kung-Kai, WONG Wing-Tak. Syntheses and Crystal Structures of Transitional Metal Complexes with Polypyridines as Ligands[J]. Chem. J. Chinese Universities, 2000, 21(1): 5.

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Syntheses and Crystal Structures of Transitional Metal Complexes with Polypyridines as Ligands

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