Synthesis and Crystal Structure of a Tetranuclear Silver Cluster Complex with Selenophenolate Ligand [Me4N]2[Ag4(SePh)6]·CH3OH

Abstract

Abstract: The title complex was prepared from the reaction of PhSeH, Et₃N, AgNO₃and Me₄NCL IN CH₃CN/MeO Hunder a nitrogen atmosphere. The colorless, airsensitive crystal belongs to the monoclinic system with space group P2₁/c, a=1.7094(3) nm, b=15626(3) nm, c=2.1237(4) nm,β =110.83(3), V=5.3017(17)nm³, D_c=1.940 g/cm³, Z=4. The final Ris 0.0809 for 6938 reflection. The structure of the title complex is built up by Ag₄Se₆adamatanetype cluster anion and bulky cation. The structure of the title cluster anion [Ag₄(SePh)₆]^2-can be considered as a tetrahedron of silver atoms inscribed in a distorted octahedron of selenium atoms. The silver atoms are in a distorted trigonal planar coordination by three μ₂-selenium atoms.

Key words: Tetranuclear silver cluster anion, Selenophenolate, Crystal structure

CLC Number:

O614.122

TrendMD:

JIN Xiang-Lin, TANG Ka-Luo, LONG Yao-Ling, LIANG Yu, TANG You-Qi . Synthesis and Crystal Structure of a Tetranuclear Silver Cluster Complex with Selenophenolate Ligand [Me₄N]₂[Ag₄(SePh)₆]·CH₃OH[J]. Chem. J. Chinese Universities, 1999, 20(6): 831.

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Synthesis and Crystal Structure of a Tetranuclear Silver Cluster Complex with Selenophenolate Ligand [Me₄N]₂[Ag₄(SePh)₆]·CH₃OH

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