The Synthesis,Characterization of New Metal bisdithiole Complexes M-BDT and Indexing on Polycrystalline Xray Diffraction Pattern

Abstract

Abstract: Four new M-BDTcomplexes were prepared for the first time(M=Ni, BDT is dithiole with nine Satoms).The study of elementary analysis, IR spectra and UV spect rashows that The molecular formula of The four compounds can be ex pressed as[(CH₃)₄N]₂[Ni(C₅S₉)₂](1), [(C₂H₅)₄N]₂[Ni(C₅S₉)₂](2), [(C₄H₉)₄N]₂[Ni(C₅S₉)₂](3), [(C₆H₅)(CH₃)₃N]₂[Ni(C₅S₉)₂](4), respectively.The Xray pow der diff raction pattern of compound 1 was deter m ined and its Xray diff raction lines were indexed.The indexing results show that The cryst al be longs to The monoclinic system with a simple monoclinic latice.The cell parameters of The crystal of complex 1:a=0.680 nm, b=0.714 nm, c=2.302 nm, =1114, Z=2.

Key words: Complex, Dithiole, Crystal structure

CLC Number:

O614.8

TrendMD:

HAO Zhi-Feng, YU Xiang-Yang, PANG Shu-Feng, LI Yong-LI, TANG Zong-Xun, SHI Qi-Zhen . The Synthesis,Characterization of New Metal bisdithiole Complexes M-BDT and Indexing on Polycrystalline Xray Diffraction Pattern[J]. Chem. J. Chinese Universities, 1999, 20(1): 9.

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The Synthesis,Characterization of New Metal bisdithiole Complexes M-BDT and Indexing on Polycrystalline Xray Diffraction Pattern

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