Syntheses and Structures of Na2[ZnⅡ(ida)2]·7H2O and Na4[HgⅡ(nta)2]·7H2O

Abstract

Abstract: The title complexes were synthesized and the crystal structures of their salts were determined by single crystal X-ray structure analyses. Na₂[Zn^Ⅱ(ida)₂]·7H₂O: Triclinic, P1, a =0.5234(2) nm, b =0.89710(10) nm, c =1.06910(10) nm, α =85.910(10)°, β = 76.380(10)°, γ =83.52(2)°, V =0.4842(2) nm³, Z =1. The complex anion [Zn^Ⅱ(ida)₂]^2- has a pseudo octahedral structure in which the two Natoms are in a trans configuration. Na₄[Hg^Ⅱ(nta)₂] ·7H₂O: Monoclinic, C_c, a =1.7980(4) nm, b =0.8929(2) nm, c = 1.5754(2) nm, β =92.78(3)°, V =2.5262(9) nm³, Z =4. The complex anion [Hg^Ⅱ(nta)₂]^4- has a pseudo bicapped octahedral structure in which the two Natoms are in a trans configuration.

Key words: Zn^Ⅱ, Hg^Ⅱ, Aminodiacetate, Aminotriacetate, Complex

CLC Number:

O614.24

TrendMD:

WANG Jun, ZHANG Wei-Qun, ZHANG Xiang-Dong, XING Yan, LIN Yong-Hua, JIA Heng-Qing . Syntheses and Structures of Na₂[Zn^Ⅱ(ida)₂]·7H₂O and Na₄[Hg^Ⅱ(nta)₂]·7H₂O[J]. Chem. J. Chinese Universities, 1998, 19(4): 517.

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Syntheses and Structures of Na₂[Zn^Ⅱ(ida)₂]·7H₂O and Na₄[Hg^Ⅱ(nta)₂]·7H₂O

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