Fourier Transform Infrared Photoacoustic Spectroscopy of Tetra(para-octanoyloxyphenyl)Porphyrin Complexes

Abstract

Abstract: The fourier transform infrared photoacoustic spectra of tetra-(para octanoyloxyphenyl) porphyrin T(p-OO)PPH₂ and its Mn(Ⅲ), Fe(Ⅲ), Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ) and Zn(Ⅱ) complexes in the range of 3600～190 cm^-1 were measured and investigated. The bands at 3318.0 and 968.0 cm^-1 of T(p-OO)PPH₂ are due to the N—Hstretching and in plane and out-plane bending vibration of the pyrrole groups. All these bands disappear upon complexes formation. The vibration coupling between the M—N stretching and the porphyrin ring deformation appears at 243 cm^-1. Metal sensitive bands were found at 1504, 1350, 1022, 995, 796 and 235 cm^-1.

Key words: Tetra (para octanoyloxyphenyl) porphyrin, Complex, Infrared photoacoustic spectrum, Porphyrin, Porphyrin derivatives with long carbon chain

CLC Number:

O657.33

TrendMD:

SHI Tong-Shun, LIU Wei, WANG Yin-Jie, ZHAO Jun, LIU Guo-Fa . Fourier Transform Infrared Photoacoustic Spectroscopy of Tetra(para-octanoyloxyphenyl)Porphyrin Complexes[J]. Chem. J. Chinese Universities, 1998, 19(11): 1794.

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Fourier Transform Infrared Photoacoustic Spectroscopy of Tetra(para-octanoyloxyphenyl)Porphyrin Complexes

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