Synthesis and Crystal Structure of Trihalostannane and Tungsten(molybdenum) Bonded Bimetallic Complexes

Abstract

Abstract: The substitution reaction of CpM (CO)₃SnPh₃ or CpM (CO)₃SnPh₂X (Cp=C₅H₄CH₃, C₅H₄COCH₃;M=Mo, W; X=Cl, Br) with HCl or HBr yielded trihalo- or mixed trihalostannane tungsten(molybdemun) bonded bimetallic complexes, which were character-ized by elementary analysis, ¹H NMRand IR. Crystals of complex Cl₃SnW(CO)₃C₅H₄·COCH₃ are monoclinic, space group P2₁/c, a=0.7686(3)nm, b=1.2622(2)nm, c=1.6022(2)nm, β=102.13(2)°, Z=4, μ=97.45cm^-1, V=1. 5197(7)nm³. The bond dis-tance of Sn-Wbond is 0.27361(8)nm.

Key words: Trihalostannane, Substitution reaction, Crystal structure

CLC Number:

O641.4

TrendMD:

HE Hai-Yang, XU Yu-Ming, WANG Ji-Tao, SUN Jie, KONG Xiang-Fu. Synthesis and Crystal Structure of Trihalostannane and Tungsten(molybdenum) Bonded Bimetallic Complexes[J]. Chem. J. Chinese Universities, 1997, 18(8): 1329.

References

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