The Reactioll Process and Structure of Polyaniline Thermal Doped with Dodccylbenzenesulfonate

Abstract

Abstract: The distinguishing features and structures of polyaniline thermal doped with dodecylbenzenesulfonate at different temperatures without the use of auxiliary solvent have been investigated.The exothermic complexion has been observed during doping process at elevated temperature by calorimeter studies, which results in the formation of a transition responslble for the del0calized polarons observed by UV-Vis spectrum.The resulting complex is shown to form a layered structure with strongly anisotropic characteristics as determined by X-ray diffraction measurement.

Key words: Polyaniline, Dodecylbenzenesulfonate, Thermal doping

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ZHENG Yu-Dong, LI Ji-Bo, HUANG Jiong-Liang. The Reactioll Process and Structure of Polyaniline Thermal Doped with Dodccylbenzenesulfonate[J]. Chem. J. Chinese Universities, 1997, 18(3): 495.

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The Reactioll Process and Structure of Polyaniline Thermal Doped with Dodccylbenzenesulfonate

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