Chem. J. Chinese Universities ›› 1996, Vol. 17 ›› Issue (6): 854.

• Articles • Previous Articles     Next Articles

A Study of Tetraaza[14] Annulene Nickel(Ⅱ) Complexes(Ⅰ)──Syntheses and Characterizations of Substituted Tetraaza[14]Annulene Nickel(Ⅲ) Complexes

ZHANG Wen-Wei, LI Dong-Wen, XU Er-Jie, MENG Qing-Jin, YOU Xiao-Zeng   

  1. The Coordinarion Chemistry Institute, Nanjing University, Nanjing 210093
  • Received:1995-05-30 Online:1996-06-24 Published:1996-06-24

Abstract: The property of tetraaza[14] annulene complexes is very similar to that of porphyrin and phthalocyanin compounds.In this paper, two tetraaza[14] annulene nickil (Ⅱ)macrocycles were synthesized by the reaction of template effect,six dibenzoyl tetraaza[14]annulene complexes were prepared by the electrophilic substitutions, which have not been reported before.All were characterized by EA, IR, UV, 1H NMR, MS.

Key words: Tetraaza annulene, Complex, Spectra characterization

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