The Temperature Effect of Microelectrode and Its Applications to the Determination of Kinetic Parameters

Chem. J. Chinese Universities ›› 1996, Vol. 17 ›› Issue (2): 224.

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The Temperature Effect of Microelectrode and Its Applications to the Determination of Kinetic Parameters

ZHUANG Qian-Kun, CHEN Hong-Yuan

Department of Chemistry, Nanjing University, Nanjing 210093

Received:1995-02-21 Online:1996-02-24 Published:1996-02-24

Abstract

Abstract: The temperature effect of microelectrode has been studied in detail.Anew simple method for the determination of the diffusion coefficient,activation energy and the catalytic rate constant on the basis of the temperature effect at the microdisk electrode has been developed.The experimental results for several systems are in a good agreement with those obtained by other methods in literatures.

Key words: Microelectrode, Steady-state current, Temperature effect, Kinetic parameters

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ZHUANG Qian-Kun, CHEN Hong-Yuan. The Temperature Effect of Microelectrode and Its Applications to the Determination of Kinetic Parameters[J]. Chem. J. Chinese Universities, 1996, 17(2): 224.

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The Temperature Effect of Microelectrode and Its Applications to the Determination of Kinetic Parameters

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