Studies on the Interaction Between the Layers and Pillars of Hydrotalcite-Like Compounds Pillared with Heteropolyanions

Chem. J. Chinese Universities ›› 1995, Vol. 16 ›› Issue (9): 1329.

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Studies on the Interaction Between the Layers and Pillars of Hydrotalcite-Like Compounds Pillared with Heteropolyanions

LIU Ji-Guang¹, GUO Jun¹, SUN Tie¹, LU Hui-Juan¹, MAO Li-Qiu¹, JIANG Da-Zhen¹, MIN En-Ze²

1. Department of Chemistry, Jilin University, Changchun 130023;
2. Research Institute of Petroleum Processing, Beijing, 100083

Received:1994-10-13 Revised:1995-03-20 Online:1995-09-24 Published:1995-09-24

Abstract

Abstract: Hydrotalcite-like compounds (HTIs),heteropolyanions with different composetions,and their pillared products were prepared.The interactions between the layers and pillars of the pillared products were investigated by IR spectra and DTA methods. Tge results show that the M³⁺ions in the HTIs and the component elements of the heteropolyanions with Keggin structure, which can either exist in the tetrahedral or in the octahedral positions, have significant effects on the interactions between the layers and pillars. In addition,this interaction usually results in changes in the symmetry and relative properties of the heteropolyanions.

Key words: Heteropolyanions, Hydrotalcite-Like compounds, Layers, Pillars, Interaction

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LIU Ji-Guang, GUO Jun, SUN Tie, LU Hui-Juan, MAO Li-Qiu, JIANG Da-Zhen, MIN En-Ze. Studies on the Interaction Between the Layers and Pillars of Hydrotalcite-Like Compounds Pillared with Heteropolyanions[J]. Chem. J. Chinese Universities, 1995, 16(9): 1329.

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Studies on the Interaction Between the Layers and Pillars of Hydrotalcite-Like Compounds Pillared with Heteropolyanions

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