Studies on the Synthesis of Dipentyl Phthalate Using Hydrotalcite-Containing Rare Earth as a Catalyst

Chem. J. Chinese Universities ›› 1995, Vol. 16 ›› Issue (8): 1164.

• Articles • Previous Articles Next Articles

Studies on the Synthesis of Dipentyl Phthalate Using Hydrotalcite-Containing Rare Earth as a Catalyst

LI Lian-Sheng¹, MA Shu-Jie¹, HUI Jian-Bin¹, LIU Xin-Sheng¹, XU Ru-Ren¹, BAO Yu-Min²

1. Department of Chemistry, Jilin Universtity, Changchun, 130023;
2. Department of Chemistry, Inner Mongolia Nationalities Teacher' s College

Received:1994-11-17 Revised:1995-01-20 Online:1995-08-24 Published:1995-08-24

Abstract

Abstract: Synthesis of dipentyl phthalate using hydrotalcite-containing rare earth as a catalyst is studied in detail,involved influence of amount of the catalyst,mole ratio of phthalic anhydride to n-pentanol,reaction temperature and time on the conversion of phthalic anhydride to dipentyl phthalate. The results show that the catalyst has a high catalytic activity and high selectivity,and the conversion is up to 95%.La content in the catalyst may change in a certain range and the conversion of phthalic anhydride increases with increasing of La content.The surface area of the catalyst calcined at 400℃ is about 120m²/g (BET/N₂technique). It has Lewis and Bronsted acid sites and the amount of Lewis acid is far more than that of Bronsted acid.The mole ratio of chemical composition of the catalyst is Mg:Al:La=6:(2-x):x, where 0≤x≤1.0.

Key words: Hydrotalcite, Rare earth, Catalyst

TrendMD:

LI Lian-Sheng, MA Shu-Jie, HUI Jian-Bin, LIU Xin-Sheng, XU Ru-Ren, BAO Yu-Min. Studies on the Synthesis of Dipentyl Phthalate Using Hydrotalcite-Containing Rare Earth as a Catalyst[J]. Chem. J. Chinese Universities, 1995, 16(8): 1164.

[1]	CHU Yuyi, LAN Chang, LUO Ergui, LIU Changpeng, GE Junjie, XING Wei. Single-atom Cerium Sites Designed for Durable Oxygen Reduction Reaction Catalyst with Weak Fenton Effect [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220294.
[2]	YANG Jingyi, LI Qinghe, QIAO Botao. Synergistic Catalysis Between Ir Single Atoms and Nanoparticles for N₂O Decomposition [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220388.
[3]	LIN Gaoxin, WANG Jiacheng. Progress and Perspective on Molybdenum Disulfide with Single-atom Doping Toward Hydrogen Evolution [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220321.
[4]	REN Shijie, QIAO Sicong, LIU Chongjing, ZHANG Wenhua, SONG Li. Synchrotron Radiation X-Ray Absorption Spectroscopy Research Progress on Platinum Single-atom Catalysts [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220466.
[5]	TENG Zhenyuan, ZHANG Qitao, SU Chenliang. Charge Separation and Surface Reaction Mechanisms for Polymeric Single-atom Photocatalysts [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220325.
[6]	WANG Ruyue, WEI Hehe, HUANG Kai, WU Hui. Freezing Synthesis for Single Atom Materials [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220428.
[7]	QIN Yongji, LUO Jun. Applications of Single-atom Catalysts in CO₂ Conversion [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220300.
[8]	FAN Jianling, TANG Hao, QIN Fengjuan, XU Wenjing, GU Hongfei, PEI Jiajing, CEHN Wenxing. Nitrogen Doped Ultra-thin Carbon Nanosheet Composited Platinum-ruthenium Single Atom Alloy Catalyst for Promoting Electrochemical Hydrogen Evolution Process [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220366.
[9]	LIN Zhi, PENG Zhiming, HE Weiqing, SHEN Shaohua. Single-atom and Cluster Photocatalysis： Competition and Cooperation [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220312.
[10]	CHENG Qian, YANG Bolong, WU Wenyi, XIANG Zhonghua. S-doped Fe-N-C as Catalysts for Highly Reactive Oxygen Reduction Reactions [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220341.
[11]	WEI Chunhong, JIANG Qian, WANG Panpan, JIANG Chengfa, LIU Yuefeng. Atomic Scale Investigation of Pt Atoms/clusters Promoted Co-catalyzed Fischer-Tropsch Synthesis [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220074.
[12]	ZHANG Xinxin, XU Di, WANG Yanqiu, HONG Xinlin, LIU Guoliang, YANG Hengquan. Effect of Mn Promoter on CuFe-based Catalysts for CO₂ Hydrogenation to Higher Alcohols [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220187.
[13]	ZHAO Runyao, JI Guipeng, LIU Zhimin. Efficient Electrocatalytic CO₂ Reduction over Pyrrole Nitrogen-coordinated Single-atom Copper Catalysts [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220272.
[14]	ZHOU Leilei, CHENG Haiyang, ZHAO Fengyu. Research Progress of CO₂ Hydrogenation over Pd-based Heterogeneous Catalysts [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220279.
[15]	SONG Youwei, AN Jiangwei, WANG Zheng, WANG Xuhui, QUAN Yanhong, REN Jun, ZHAO Jinxian. Effects of Ag，Zn，Pd-doping on Catalytic Performance of Copper Catalyst for Selective Hydrogenation of Dimethyl Oxalate [J]. Chem. J. Chinese Universities, 2022, 43(6): 20210842.

Studies on the Synthesis of Dipentyl Phthalate Using Hydrotalcite-Containing Rare Earth as a Catalyst

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments