Crystal Structure and Spectra of Eu(β-NMA)3(PHEN)

Chem. J. Chinese Universities ›› 1995, Vol. 16 ›› Issue (4): 500.

• Articles • Previous Articles Next Articles

Crystal Structure and Spectra of Eu(β-NMA)₃(PHEN)

LI Lin-Shu¹, WANG Rui-Fen¹, JIN Lin-Pei², CAI Guan-Liang³

1. Department of Chemistry, Hebei Teachers'College, Shijiazhuang, 050091;
2. Department of chemistry, Beijing Normal University;
3. Institute of Chemical Defence, PLA of China

Received:1994-04-15 Revised:1994-07-13 Online:1995-04-24 Published:1995-04-24

Abstract

Abstract: The title compound belongs to triclinic system with a space group 1,a=1. 1718 (2)nm,b=1.5670(3)nm,c=1.0002(2)nm;α=99.97(1)°,β=90.13(1)°,γ=98.36(2)°,M=845. 68,V= 1.7889(5)nm³,Z=2,F(000)=848,D_x=1.57g·cm^-3,λ(Mo Kα)=0.071069 nm,μ=18. 06 cm^-1,T=295K. The structure was solved by heavy-atom method and refined by full-matrix least squares technique for 54 non-hydrogen atoms and anisotropically for 4961 reflections with I>3σ(I). The final Ris 0.040.Center Eu(Ⅲ)ion is octa-coordinated wiht six oxygen atom of three β-NMA molecules and two nitrogen atoms of PHEN, giving the square antiprism with C₁ site symmetry for the Eu(Ⅲ)ion.

Key words: Europium, Ternary complex, Crystal structure

TrendMD:

LI Lin-Shu, WANG Rui-Fen, JIN Lin-Pei, CAI Guan-Liang. Crystal Structure and Spectra of Eu(β-NMA)₃(PHEN)[J]. Chem. J. Chinese Universities, 1995, 16(4): 500.

References

Related Articles 15

[1]	LIU Qingqing, WANG Pu, WANG Yongshuai, ZHAO Man, DONG Huanli. Synthesis and Topochemical Polymerization Study of Naphthalene/perylene Imides Substituted Diacetylene Derivatives [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220091.
[2]	SHI Naike, ZHANG Ya, SANSON Andrea, WANG Lei, CHEN Jun. Uniaxial Negative Thermal Expansion and Mechanism in Zn（NCN） [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220124.
[3]	YUE Shengli, WU Guangbao, LI Xing, LI Kang, HUANG Gaosheng, TANG Yi, ZHOU Huiqiong. Research Progress of Quasi-two-dimensional Perovskite Solar Cells [J]. Chem. J. Chinese Universities, 2021, 42(6): 1648.
[4]	TIAN Xia,YANG Fuqun,YUAN Wei,ZHAO Lei,YAO Lei,ZHEN Xiaoli,HAN Jianrong,LIU Shouxin. Synthesis, Structure and Recognition Properties of Macrocyclic Crown Ethers with Oxadiazole ^† [J]. Chem. J. Chinese Universities, 2020, 41(3): 490.
[5]	LIU Dongmei,SU Yajing,LI Shanshan,XU Qiwei,LI Xia. Transition Metal Coordination Polymers Constructed by 4-(4-Carboxyphenoxy)isophthalic Acid: Synthesis, Crystal Structure, Fluorescence Sensing and Photocatalysis ^† [J]. Chem. J. Chinese Universities, 2020, 41(2): 253.
[6]	QIN Liulei,LIU Yang,GUAN Xiaoqin,ZHENG Xiaoyuan,ZHANG Ziyu,LIU Zunqi. Synthesis and Switchable Dielectric Properties of an Inorganic-organic Hybrid Complex [H₂(DABCO)CuCl₄]·H₂O ^† [J]. Chem. J. Chinese Universities, 2020, 41(1): 70.
[7]	LI Bing,WANG Xuemin,BAI Fengying,LIU Shuqing. Synthesises, Structures and Antibacterial Activities of a Series of Rare Earth Nitrogen Heterocyclic Complexes^† [J]. Chem. J. Chinese Universities, 2019, 40(4): 632.
[8]	YANG Weiqiang, ZHANG Guiyun, LIN Hua, NI Jiancong, HUANG Lingfeng. Ratiometric Fluorescence Assay for Visual Detection of Tetracycline Residues based on the Complex of Carbon Dots and Europium ^† [J]. Chem. J. Chinese Universities, 2019, 40(11): 2294.
[9]	ZHANG Chunyan,LUO Jianxin,LI Wenjun,OU Lijuan,YU Guipeng,PAN Chunyue. Preparation and Sensing Properties of Covalent-linked Europium Complex Monodisperse Polystyrene Microspheres^† [J]. Chem. J. Chinese Universities, 2019, 40(1): 153.
[10]	WANG Dongmei,LIU Zihua,LI Guanghua,LIU Yunling,LI Chunxia. Synthesis, Structure and Fluorescent Property of Indium-based Bimetallic Metal-organic Frameworks^† [J]. Chem. J. Chinese Universities, 2018, 39(9): 1886.
[11]	TIAN Huan, ZHANG Menglong, WANG Lisha, TONG Bihai, ZHAO Zhuo. Synthesis of 4,13-Dithio Benzene and-18-Crown-6 and Its Selective Extractability on A $g + †$ [J]. Chem. J. Chinese Universities, 2018, 39(6): 1191.
[12]	ZHU Lei,HAN Junyan,CHANG Haizhen,QIU Yuyuan,ZHANG Yanan,PENG Danni,HU Wei,MIAO Shaobin. Different Pathways for the Cyclocondensation Reactions of 1,2-Diamine and 1,2-Diketone^† [J]. Chem. J. Chinese Universities, 2018, 39(12): 2686.
[13]	LI Zheng, LI Rui, LI Xia. Synthesis, Crystal Structure and Fluorescent Properties of Transition Metal Complexes Constructed with 2-(3'-Carboxyphenoxy)benzoic Acid and N-Donor Ligands^† [J]. Chem. J. Chinese Universities, 2018, 39(11): 2363.
[14]	CHEN Qidan, TANG Junjie, FANG Qianrong. Highly Stable Fluorine Containing Hierarchical Porous Covalent Organic Framework^† [J]. Chem. J. Chinese Universities, 2018, 39(11): 2357.
[15]	LI Jian,XIE Linxia,LIANG Zupei,GUO Rong,LIU Chenyu,MA Shulan. Luminescence Property and Detection Capability Towards Hg²⁺ of LEuH Composites with Mo $S 4 2 -$ and OS^- Anions^† [J]. Chem. J. Chinese Universities, 2018, 39(10): 2154.

Crystal Structure and Spectra of Eu(β-NMA)₃(PHEN)

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments