Research on the Synthesis of New Silver Cluster Complexes by the Insertion Reaction of CS2into Ag──S Bonds(Ⅲ)── Formation and Crystal Structure of a Trinuclear Silver Cluster Complex Ag3(Pr3iC6H2S)3(PPh3)3·(CH3)2CHOH

Chem. J. Chinese Universities ›› 1995, Vol. 16 ›› Issue (3): 334.

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Research on the Synthesis of New Silver Cluster Complexes by the Insertion Reaction of CS₂into Ag──S Bonds(Ⅲ)── Formation and Crystal Structure of a Trinuclear Silver Cluster Complex Ag₃(Pr₃ⁱC₆H₂S)₃(PPh₃)₃·(CH₃)₂CHOH

JIN Xiang-Lin, TANG Ka-Luo, LIU Wei-Dong, TANG You-Qi

Institute of Physical Chemistry, Peking University, Beijing 100871

Received:1994-07-20 Revised:1994-10-22 Online:1995-03-24 Published:1995-03-24

Abstract

Abstract: The title complex was prepared through the reaction of(PPh₃)₂Ag(S₂CSPr₃ⁱC₆H₂)formed by inserting of CS₂ into Ag-S bond of Ag(SPr₃ⁱC₆H₂) in the presence of PPh₃ with CH₂Cl₂-PrⁱOH under mild conditions.The colorless block crystal belongs to the trigonal system with space group R3,a=2.7886(11)nm,c=1.0798(5)nm,V=5.796(4)nm³,D_c=1.2859.cm^-3,Z=3.The final Ris 0.060 for 1753 reflections (F>4.0σ(F)).The core of the title compound can be considered as a planar six-membered cycle Ag₃S₃ of alternating silver and sulfur atoms. In addition,there exists a PrⁱOH molecule in the unit cell.

Key words: Insertion reaction of CS₂, Crystal structure, Silver cluster complex, Activated molecular fragment, Self-assembly

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JIN Xiang-Lin, TANG Ka-Luo, LIU Wei-Dong, TANG You-Qi . Research on the Synthesis of New Silver Cluster Complexes by the Insertion Reaction of CS₂into Ag──S Bonds(Ⅲ)── Formation and Crystal Structure of a Trinuclear Silver Cluster Complex Ag₃(Pr₃ⁱC₆H₂S)₃(PPh₃)₃·(CH₃)₂CHOH[J]. Chem. J. Chinese Universities, 1995, 16(3): 334.

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Research on the Synthesis of New Silver Cluster Complexes by the Insertion Reaction of CS₂into Ag──S Bonds(Ⅲ)── Formation and Crystal Structure of a Trinuclear Silver Cluster Complex Ag₃(Pr₃ⁱC₆H₂S)₃(PPh₃)₃·(CH₃)₂CHOH

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