Application of Fourier Transform Infrared Photoacoustic Spectroscopy to Porphyrins Studies(Ⅲ)──FTIR-PAS of Lanthanide Acetylacetonate-meso-Tetra(para-chlorophenyl)Porphyrin Rare Earth Complexes

Chem. J. Chinese Universities ›› 1995, Vol. 16 ›› Issue (1): 94.

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Application of Fourier Transform Infrared Photoacoustic Spectroscopy to Porphyrins Studies(Ⅲ)──FTIR-PAS of Lanthanide Acetylacetonate-meso-Tetra(para-chlorophenyl)Porphyrin Rare Earth Complexes

SHI Tong-Shun, LIU Guo-Fa, YU Lian-Xiang, CAO Xi-Zhang

Department of Chemistry, Jilin University, Changchun, 130023

Received:1994-01-31 Revised:1994-07-21 Online:1995-01-24 Published:1995-01-24

Abstract

Abstract: The fourrier transform infrared photoacoustic spectra of tetra-(parachlorophenyl)porphyrin and its coordination compounds LnT(p-Cl)PPacac(Ln:Nd,Sm,Eu Gd,Tb,Dy,Ho,Er,Lu)in the range of 3600-220 cm^-1were measured and investigated. Because of the coordination bonding between the rare earth ion and nitrogen in LnT(p-Cl)PPacac forms,the band near 400 cm^-1and M-O stretching vibration on the acetylacetonate ring become weaker,and shifted to the lower wavenumber. Metal sensitive bands were found at about 1558,1474,1427,1219,798,733 and 250 cm^-1.

Key words: Infrared photoacoustic spectra, Rare earth metal, Porphyrin

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SHI Tong-Shun, LIU Guo-Fa, YU Lian-Xiang, CAO Xi-Zhang. Application of Fourier Transform Infrared Photoacoustic Spectroscopy to Porphyrins Studies(Ⅲ)──FTIR-PAS of Lanthanide Acetylacetonate-meso-Tetra(para-chlorophenyl)Porphyrin Rare Earth Complexes[J]. Chem. J. Chinese Universities, 1995, 16(1): 94.

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Application of Fourier Transform Infrared Photoacoustic Spectroscopy to Porphyrins Studies(Ⅲ)──FTIR-PAS of Lanthanide Acetylacetonate-meso-Tetra(para-chlorophenyl)Porphyrin Rare Earth Complexes

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