Immobilization and Characterization of Porphyrin and Study of Its CatalyticCapability

Chem. J. Chinese Universities ›› 1994, Vol. 15 ›› Issue (6): 789.

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Immobilization and Characterization of Porphyrin and Study of Its CatalyticCapability

WANG Xing-Qiao¹, GAO Shuang¹, LIU Yu-Wen¹, YU Lian-Xiang¹, LIU Yang¹, CAO Xi-Zhang¹, WU Zhi-Yun², CUI Yue-Yong²

1. Department of Chemistry, Jilin University, Changchun, 130023;
2. Synthetic and Catalytic Academy, Jilin University, Changchun

Received:1993-08-19 Revised:1994-02-18 Online:1994-06-24 Published:1994-06-24

Abstract

Abstract: Astepwish synthesis method was used to encapsulate tetrahalogen-tetramethyl porphyrins in the supercages of NaCoXmolecular sieve, The resulting samples were washed with DMFin a Soxhiet extractor untill the porphyrin which deposited on the external surface of molecular sieve was removed completely.Charaterization of TCTMPand TBTMPwas made by the methods of UV-Vis, IR, SEM, DTAand absorption.Catalytic capabilities of porphyrin, molecular sieve and NaCoXmolecular sieve with supercage structure in which porphyrin was entrapped were compared.

Key words: Porphyrin, Porphyrin immobilization, Catalytic capability

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WANG Xing-Qiao, GAO Shuang, LIU Yu-Wen, YU Lian-Xiang, LIU Yang, CAO Xi-Zhang, WU Zhi-Yun, CUI Yue-Yong. Immobilization and Characterization of Porphyrin and Study of Its CatalyticCapability[J]. Chem. J. Chinese Universities, 1994, 15(6): 789.

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Immobilization and Characterization of Porphyrin and Study of Its CatalyticCapability

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