Studies on the Extraction Mechanism of Molybdenum by Primary Amine N1923 in Kerosene

Chem. J. Chinese Universities ›› 1994, Vol. 15 ›› Issue (11): 1588.

• Articles • Previous Articles Next Articles

Studies on the Extraction Mechanism of Molybdenum by Primary Amine N1923 in Kerosene

ZENG Ping, HU Jing-Yu

Department of Chemistry, Xiangtan university, Xiangtan, 411105

Received:1993-12-30 Revised:1994-04-04 Online:1994-11-24 Published:1994-11-24

Abstract

Abstract: The extraction of Mo(Ⅵ)by primary amine(abbreviated as N1923 or RNH₂)in kerosene has been investigated.The effects of pHof the aqueous phase and temperature on this extraction process have been examined. The composition of extracted compound has been determined by equimolar series method, molar ratio method and saturation experiment.The infra-red spectra of the organic phase have also been studied.The mechanism of extraction is discussed.

Key words: Primary amine, Molybdenum, Extraction mechanism, Extracted compound

TrendMD:

ZENG Ping, HU Jing-Yu. Studies on the Extraction Mechanism of Molybdenum by Primary Amine N1923 in Kerosene[J]. Chem. J. Chinese Universities, 1994, 15(11): 1588.

[1]	LIN Gaoxin, WANG Jiacheng. Progress and Perspective on Molybdenum Disulfide with Single-atom Doping Toward Hydrogen Evolution [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220321.
[2]	BI Gening, XIAO Xiaohua, LI Gongke. Development and Validation of Multiple Physical Fields Coupling Model for Microwave-assisted Extraction [J]. Chem. J. Chinese Universities, 2022, 43(3): 20210739.
[3]	ZHANG Nan, HAN Kuo, LI Yue, WANG Chunru, ZHAO Feng, HAN Dongxue, NIU Li. Core-shell Heterostructure Construction Between Thiospinel CuCo₂S₄ and MoS₂ for Improved Hydrogen Evolution Electrocatalytic Performance [J]. Chem. J. Chinese Universities, 2021, 42(4): 1307.
[4]	CHEN Xiaoyu, YU Ranbo. Research Progress on Doping of Molybdenum Disulfide and Hydrogen Evolution Reaction [J]. Chem. J. Chinese Universities, 2021, 42(2): 475.
[5]	CUI Jinping, CHEN Wenxian, YU Feifan, CAO Shiyu, LYU Weiyang, YAO Yuyuan. Adsorption Reduction of Hexavalent Chromium and co-Catalytic Degradation of Organic Pollutants by Carbon Doped Hexagonal Boron Nitride Supported MoS₂ [J]. Chem. J. Chinese Universities, 2021, 42(10): 3125.
[6]	XIA Xiaoli,TAN Jingjing,WEI Caiyun,ZHAO Yongxiang. Molybdenum Modified Nickel Phyllosilicates Catalyst for Maleic Anhydride Hydrogenation^† [J]. Chem. J. Chinese Universities, 2019, 40(6): 1207.
[7]	HE Caimei,ZHENG Jingyi,LI Xiaoxia. MoS₂-Gold Nanoparticles and Thionine-gold Nanoparticle Based Signal-enhanced Electrochemical Aptasensor for the Detection of 17β-Estradiol ^† [J]. Chem. J. Chinese Universities, 2019, 40(10): 2090.
[8]	LI Jianwei,LI Xiang,ZHANG Jie,LEI Zhigang. Mechanism of the Interaction Between Ionic Liquid [Bmim][DBP] and Methanol for Seperation of Mixed C₄/Methanol^† [J]. Chem. J. Chinese Universities, 2018, 39(5): 983.
[9]	FENG Huijie, ZHENG Wenjun. Synthesis of MoS₂ Hierarchical Nanostructure and Its Performance for Lithium-ion Battery^† [J]. Chem. J. Chinese Universities, 2017, 38(7): 1134.
[10]	LIU Renzhi, LI Xiaoyan. Preparation of MoS₂ Hollow Nanospheres and Application in Ultrasensitive Electrochemical Biosensing Platform for Micro-RNA Detection^† [J]. Chem. J. Chinese Universities, 2017, 38(3): 383.
[11]	HU Jie, WANG Yong, NI Yongnian. Colorimetric Detection of Tin(Ⅱ) Ions Based on Layered Molybdenum Disulfide Nanosheets^† [J]. Chem. J. Chinese Universities, 2016, 37(3): 448.
[12]	SONG Panshu, WANG Jun, REN Tongxiang, ZHOU Tao, LU Hai. Novel Purification Method for Isotopically Enriched Molybdenum and Determination of Its Mass Fractionation Effect^† [J]. Chem. J. Chinese Universities, 2015, 36(2): 248.
[13]	ZHANG Shu-Yuan, JIANG Ping-Ping, LENG Yan, XU Yu-Cheng, MO Guan-Tian, BIAN Gang. Synthesis of cis-Dioxomolybdenum(Ⅵ)-tridentate Schiff Base Complexes and Its Catalytic Activity on the Epoxidation of Soybean Oil [J]. Chem. J. Chinese Universities, 2013, 34(7): 1703.
[14]	WANG Huan-Yi, LIU Tao, HE Zhan-Feng, WANG Xiao-Wei, CHEN Jun-He, WANG Juan-Yun, JIANG Yi. Glycerol Dehydration and Consecutive Hydrogen Transfer to Allyl Alcohol over MoO₃/SiO₂ Catalyst [J]. Chem. J. Chinese Universities, 2013, 34(3): 650.
[15]	LIU Qiu-Hua, SUN Huai-Lin. Synthesis, Structure and Si—Si Bond Stability of η6-[Tris(trimethylsilyl)phenylsilane]tricarbonylmolybdenum Complexes [J]. Chem. J. Chinese Universities, 2011, 32(7): 1537.

Studies on the Extraction Mechanism of Molybdenum by Primary Amine N1923 in Kerosene

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments