Application of Fourier Transform Infrared Photoacoustic Spectroscopy to Porphyrin Studies (Ⅰ)——Fourier Transform Infrared Photoacoustic Spectra ofTransitional Metal Porpbyrin Complexes

Abstract

Abstract: The Fourier transform infrared photoacoustic spectra of tetra-(p-nitrophenyl) porphyrin and its Cr(Ⅲ), Mn(Ⅲ), Fe(Ⅲ) Co(Ⅱ),Ni(Ⅱ), Cu(Ⅱ) and Zn(Ⅱ) complexes in the range of 3500—225 cm^-1 were measured and investigated.The bands at 3324 cm^-1 and 968 cm^-1 are N-Hvibrations of pyrrole.The bands at 986 cm^-1, 799 cm^-1, 737 cm^-1 and 629 cm^-1 are the vibrations of porphyrin ring.The bands at ～3109, ～1600, ～1520,～1350, ～850, ～825 and ～744 cm^-1 result from p-nitrobenzene of the porphyrin.Metal sensitive bands were found at ～1489, ～1076, ～737 and ～245 cm^-1.

Key words: Porphyrin, Transitional metal, Infrared photoacoustic spectra

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SHI Tong-shun, ZHANG Yuan-fu, YU Lian-xiang, CAO Xi-zhang. Application of Fourier Transform Infrared Photoacoustic Spectroscopy to Porphyrin Studies (Ⅰ)——Fourier Transform Infrared Photoacoustic Spectra ofTransitional Metal Porpbyrin Complexes[J]. Chem. J. Chinese Universities, 1992, 13(7): 977.

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Application of Fourier Transform Infrared Photoacoustic Spectroscopy to Porphyrin Studies (Ⅰ)——Fourier Transform Infrared Photoacoustic Spectra ofTransitional Metal Porpbyrin Complexes

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