Studies on the Macrocyclic Complexes of Transition Metal (Ⅳ)——The Synthesis and Properties of Schiff Base Type Macrocyclic Ligand Tetrafuran [26]-N4O4 and Its Transition Metal Complexes

Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (5): 580.

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Studies on the Macrocyclic Complexes of Transition Metal (Ⅳ)——The Synthesis and Properties of Schiff Base Type Macrocyclic Ligand Tetrafuran [26]-N₄O₄ and Its Transition Metal Complexes

ZHANG Bao-long¹, JI Zhen-ping¹, XIAO Wen-jin¹, WU Cheng-tai¹, LIANG Ying-qiu²

1. Department of Chemistry, Wuhan University, Wuhan 430072;
2. Institute of Theoretical Chemistry, Jilin University

Received:1991-04-23 Online:1992-05-24 Published:1992-05-24

Abstract

Abstract: A newly synthesized Schiff base type of macrocyclic ligand and its transition metal [Co(Ⅱ),Cu(Ⅱ),Zn(Ⅱ),Cd(Ⅱ)] complexes were investigated by elemental analysis, molar conductance, IR, MS, ¹H NMRetc.The results indicate that the planar configuration of free ligand changes with the formation of the complexes.

Key words: Macrocyclic compound, Transition metal (Co(Ⅱ), Cu(Ⅱ), Zn(Ⅱ), Cd(Ⅱ)) com-plex, IR

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ZHANG Bao-long, JI Zhen-ping, XIAO Wen-jin, WU Cheng-tai, LIANG Ying-qiu. Studies on the Macrocyclic Complexes of Transition Metal (Ⅳ)——The Synthesis and Properties of Schiff Base Type Macrocyclic Ligand Tetrafuran [26]-N₄O₄ and Its Transition Metal Complexes[J]. Chem. J. Chinese Universities, 1992, 13(5): 580.

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Studies on the Macrocyclic Complexes of Transition Metal (Ⅳ)——The Synthesis and Properties of Schiff Base Type Macrocyclic Ligand Tetrafuran [26]-N₄O₄ and Its Transition Metal Complexes

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