Studies on the Mechanism of Coordination Reaction of Porphyrins with Some Metal Ions by Fluorometry

Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (11): 1368.

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Studies on the Mechanism of Coordination Reaction of Porphyrins with Some Metal Ions by Fluorometry

LI Jia, PAN Zu-Ting, XU Mian-Yi

Department of Chemistry, Wuhan University, Wuhan 430072

Received:1991-11-15 Revised:1992-05-08 Online:1992-11-24 Published:1992-11-24

Abstract

Abstract: The present paper covers the mechanism of coordination reaction of porphyrins with some metal ions studied by fluorometry and the catalytic mechanism of some catalysts.Three kinds of porphyrins were tetrakis-(4-trimethylammoniumphenyl)porphyrin(TAPP),tetrakis-(4-sulphophenyl)porphyrin(TPPS₄)and tetrakis-(4-pyridyl)porphyrin(TPyP),The general conditions of the coordination reaction of porphyrins with metal ions were explained and concluded successfully.

Key words: Porphyrin, Fluorometry, Mechanism, Catalyst

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LI Jia, PAN Zu-Ting, XU Mian-Yi . Studies on the Mechanism of Coordination Reaction of Porphyrins with Some Metal Ions by Fluorometry[J]. Chem. J. Chinese Universities, 1992, 13(11): 1368.

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Studies on the Mechanism of Coordination Reaction of Porphyrins with Some Metal Ions by Fluorometry

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