Synthesis and Crystal Structure of Cerium Thiocyanate Complex with Tetraethylene Glycol [Ce(C8H18O5)(NCS)3(H2O)]

Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (11): 1349.

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Synthesis and Crystal Structure of Cerium Thiocyanate Complex with Tetraethylene Glycol [Ce(C₈H₁₈O₅)(NCS)₃(H₂O)]

NI Zhao-Ai, LIN Feng, XU Cheng

Department of Chemistry, Central Laboratory, Hangzhou University, Hangzhou, 310028

Received:1992-06-18 Revised:1992-09-04 Online:1992-11-24 Published:1992-11-24

Abstract

Abstract: The title complex has been synthesized.In this complex there is only one tetraethy-lene glycol that acts as a pentadentate ligand and forms a ring-like structure.The excess coordination sites are satisfied by three thiocyanate ions and one water molecule.The coordination number of cerium is 9.The crystal structure of this complex was determined as follows:P1 space group with a=0.8816(3)nm,b=1.0465(2)nm,c=1.2490(2)nm,α=86.46(1)°,β=70.90(2)°,γ=66.37(2)°,V=0.9943 nm³,Z=2.The final deviation factor R=0.049,for 3497 unique reflections[I≥3°(I₀)]

Key words: Thiocyanate cerium, Tetraethylene glycod(EO₄), Complex, Cryatal structure

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NI Zhao-Ai, LIN Feng, XU Cheng . Synthesis and Crystal Structure of Cerium Thiocyanate Complex with Tetraethylene Glycol [Ce(C₈H₁₈O₅)(NCS)₃(H₂O)][J]. Chem. J. Chinese Universities, 1992, 13(11): 1349.

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Synthesis and Crystal Structure of Cerium Thiocyanate Complex with Tetraethylene Glycol [Ce(C₈H₁₈O₅)(NCS)₃(H₂O)]

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