Synthesis and Characterization of 2,7,12,17-Tetra(methylthio)-3,8, 13,18-Tetra(benzoyIthio)tetraazaporphyrin and Its Coordination Compounds with Mg(Ⅱ), Cu(Ⅱ) and Ni(Ⅱ)

Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (1): 22.

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Synthesis and Characterization of 2,7,12,17-Tetra(methylthio)-3,8, 13,18-Tetra(benzoyIthio)tetraazaporphyrin and Its Coordination Compounds with Mg(Ⅱ), Cu(Ⅱ) and Ni(Ⅱ)

TANG Yue-qun, PENG Zheng-he, QIN Zi-bin

Department of Chemistry, Wuhan University, Wuhan, 30072

Received:1990-12-11 Online:1992-01-24 Published:1992-01-24

Abstract

Abstract: The title compounds, 2, 7,12,17-Tetra(methylthio)-3,8,13,18-tetra(benzoylthio) tetraazaporphyrin [H₂T(mbm)TAP] and its metal complexes[MT(mbm)TAP, M = Mg(Ⅱ), Cu (Ⅱ), Ni (Ⅱ)], were synthesized from l-methylthio-2-benzoylthiomaleonitrile.The new compounds were characterized by elemental analysis, IR, UV-Vis spectra and DTA.

Key words: Thio-tetraazaporphyrin, Coordination compound, Magnesium, Copper, Nickel

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TANG Yue-qun, PENG Zheng-he, QIN Zi-bin . Synthesis and Characterization of 2,7,12,17-Tetra(methylthio)-3,8, 13,18-Tetra(benzoyIthio)tetraazaporphyrin and Its Coordination Compounds with Mg(Ⅱ), Cu(Ⅱ) and Ni(Ⅱ)[J]. Chem. J. Chinese Universities, 1992, 13(1): 22.

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Synthesis and Characterization of 2,7,12,17-Tetra(methylthio)-3,8, 13,18-Tetra(benzoyIthio)tetraazaporphyrin and Its Coordination Compounds with Mg(Ⅱ), Cu(Ⅱ) and Ni(Ⅱ)

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