Chem. J. Chinese Universities ›› 1990, Vol. 11 ›› Issue (11): 1286.

• Articles • Previous Articles     Next Articles

Optimizing Design for Investigation of Catalytic-Kinetic Analysis by Multi-Object Simplex Method

Jiang Hailiang1, Li Changfeng2, Yuan Dawen3   

  1. 1. Jiangxi Analysis and Test Centre, Nanchang, 330029;
    2. Department of Mathematics, Jiangxi University, Nanchang;
    3. Department of Chemistry, ZheJiang Institute of Technology, Hangzhou
  • Received:1989-06-28 Online:1990-11-24 Published:1990-11-24

Abstract: An multi-object simplex method has been developed which shows promise as a method for accurate and rapid search of optimum conditions for catalytic kinetic analysis. This method is applied to two catalysed reaction systems in this paper. Compared with the single factor optimization, the number of experiments is reduced and the apparent molar absorptivity is increased by 30%~36%.

Key words: Catalytic-kinetic analysis, Simplex method, Penalty function, Mercury, Silver

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