Crystal Structure of 2,2'-Tetramethylene-Dioxodi(8-N- Salicylideneimino-naphthalene) Copper Complex

Abstract

Abstract: The crystal structure of the title complex was determined by X-ray diffraction. It belongs to the monoclinic system, space group is P2₁/a with cell dimensions a =9. 824(3)Å , b=35. 530(9)ÅA. c=17.552(6)Å,β=98. 97(2)°, V=6053(4)Å³ and Z=8. The structure was analyzed by Patterson and Fourier technique and refined by block-matrix least squares to final residual factor of R = 0. 064. The complex is a trans-planar "capped" structure, with average bond length Cu-O 1.870Å ,Cu-N 2.007Å. There are two crystallographically independent molecules.

Key words: Crystal structure, "Capped", complex, Cavity

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Liu Zuocai, Shao Meicheng, Tang Youqi . Crystal Structure of 2,2'-Tetramethylene-Dioxodi(8-N- Salicylideneimino-naphthalene) Copper Complex[J]. Chem. J. Chinese Universities, 1990, 11(1): 58.

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Crystal Structure of 2,2'-Tetramethylene-Dioxodi(8-N- Salicylideneimino-naphthalene) Copper Complex

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