Study on Porphyrin Compounds (Ⅸ)——Synthesis of 5-(o-Propenoylaminophenyl)-10,15,20-Triphenyl Porphyrin Polymer and Its Cobalt Complex

Chem. J. Chinese Universities ›› 1989, Vol. 10 ›› Issue (7): 683.

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Study on Porphyrin Compounds (Ⅸ)——Synthesis of 5-(o-Propenoylaminophenyl)-10,15,20-Triphenyl Porphyrin Polymer and Its Cobalt Complex

Li Pingying, Jiang Zhaoci, Huang Suqiu

Department of Chemistry, Wuhan University, Wuhan

Received:1987-11-07 Online:1989-07-24 Published:1989-07-24

Abstract

Abstract: 5- (o-propenoylaminophenyl)- 10, 15, 20-triphenylporphyrin (Ⅱ) was synthesized from acryloyl chloride and 5-(o-aminophenyl)-10,15, 20-triphenylporphyrin (Ⅰ) and was further polymerized to 5-(o-propenoylaminophenyl)-10,15,20-triphenylporphyrin polymer(Ⅲ) in the presence of initiator, and the cobalt complexes of (Ⅱ) and (Ⅲ) were also synthesized.Their chemical structures were identified by NMR, UVand IRspectra as well as elemental analysis.

Key words: Porphyrin, Monomer, Polymer, Complex

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Li Pingying, Jiang Zhaoci, Huang Suqiu . Study on Porphyrin Compounds (Ⅸ)——Synthesis of 5-(o-Propenoylaminophenyl)-10,15,20-Triphenyl Porphyrin Polymer and Its Cobalt Complex[J]. Chem. J. Chinese Universities, 1989, 10(7): 683.

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Study on Porphyrin Compounds (Ⅸ)——Synthesis of 5-(o-Propenoylaminophenyl)-10,15,20-Triphenyl Porphyrin Polymer and Its Cobalt Complex

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