Addition Reaction of Aryloxyphenylthiophosphonyl Hydrazides with Iso(thio)cyanates

Chem. J. Chinese Universities ›› 1989, Vol. 10 ›› Issue (2): 158.

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Addition Reaction of Aryloxyphenylthiophosphonyl Hydrazides with Iso(thio)cyanates

Jin Guiyu¹, Sha Yuewu¹, Cai Jianping¹, Chen Ruyu¹, Miao Fangming², Liu Xiaolan²

1. Institute of Elemento-Organic Chemistry, Nankai University, Tianjin;
2. Department of Chemistry, Tianjin Normal University, Tianjin

Received:1987-10-10 Online:1989-02-24 Published:1989-02-24

Abstract

Abstract: Some new N-thionophosphonyl- and N,N'-bis(thionophosphonyl) thio-semicarbazides were synthesized.The diastereoisomers of N,N'-(thionophosphonyl) thiosemicarbazides possessing two chiral P-atoms were separated and their structures were determined by IR, ¹HNMR, MS spectra, elemental analysis and X-ray diffraction method. The MS spectra of mono- and disubstituted thiophosphonyla-minourea were discussed.

Key words: Thionophosphonyl hydrazide, Iso(thio) cyanate, Addition, Thiono- phosphonylthiosemicarbazide

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Jin Guiyu, Sha Yuewu, Cai Jianping, Chen Ruyu, Miao Fangming, Liu Xiaolan. Addition Reaction of Aryloxyphenylthiophosphonyl Hydrazides with Iso(thio)cyanates[J]. Chem. J. Chinese Universities, 1989, 10(2): 158.

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Addition Reaction of Aryloxyphenylthiophosphonyl Hydrazides with Iso(thio)cyanates

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