Amphoteric Terramycin Sensitive Electrodes and Selectivities

Abstract

Abstract: Electrodes sensitive to cationic or anionic terramycin were constructed using, terramycinium silicotungstate, TPB, DPAand cetyltribctylammonium terramycina-te as electroactive materials. The terramycinium (terramycinate) sensitive elec-trode responds to terramycinium (terramycinate) down to 10 (40) μnol/Lover pHrange 1.6-3.2 (8.0-11.0) with a slope of ca, 57.2(-58)mV/lgC. The electrode selectivities toward quaternary ammoniums and inorganic cations are described in terms of ionic potential Z/Rand induction index I:lgK_ij = 9.87I-31.94Z/R + 290.44(R = 0.999) and lgK_ij =1.422 (Z/R)^-1-3.363. (R= 0.942).

Key words: Terramycin sensitive electrode, Determination, of terramycih, trode selectlectivity

TrendMD:

Yao Shouzhuo, Shiao Jun, Nie Lihua . Amphoteric Terramycin Sensitive Electrodes and Selectivities[J]. Chem. J. Chinese Universities, 1988, 9(6): 637.

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Amphoteric Terramycin Sensitive Electrodes and Selectivities

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