The Synthesis, Spectra and Magnetic Properties of Dibenzoyl-Bis-(Thiosemicarbazone)Copper(Ⅱ)

Abstract

Abstract: Dibenzoyl-bis-(thiosemicarbazone) C₁₆H₁₆N₆S₂ and a complex with copper(Ⅱ) Cu(C₁₆H₁₄NaS₂), were synthesized. The measurements of elemental analysis,electrical conductivity, 1Rspectra, electronic spectra, ESRspectra and magnetic susceptibility curve with temperatures (1.5~300°K) were carried out. The magnetic susceptibility data fit the modified Bleaney-Bowers dimer equation yielding J = -2.88cm^-1 and g = 2.07. The coordinated bond of the complex is strongly covalent bond and α² =0.64, P_N = 0.114, which have been suggested from ESRspectra.

Key words: Dibenzoyl-bis-(thiosemicarbazone), Complex, Magnetic suscep-tibility

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Bai Lingjun, Huang Ling, Wang Genglin . The Synthesis, Spectra and Magnetic Properties of Dibenzoyl-Bis-(Thiosemicarbazone)Copper(Ⅱ)[J]. Chem. J. Chinese Universities, 1988, 9(5): 427.

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The Synthesis, Spectra and Magnetic Properties of Dibenzoyl-Bis-(Thiosemicarbazone)Copper(Ⅱ)

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