Construction and Magnetic Properties of Low-Dimensional Ytterbium(III) Coordination Polymers Based on Formate and Oxalate Co-Ligands

doi:10.7503/cjcu20260193

Chem. J. Chinese Universities

• Article • Previous Articles

Construction and Magnetic Properties of Low-Dimensional Ytterbium(III) Coordination Polymers Based on Formate and Oxalate Co-Ligands

ZHAI　Xiaolu¹， LV　Yun¹， LI　Hui¹， HUANG　Keke²， WANG　Yanhong^1*， LU　Hongcheng^1，3

1. School of Chemistry and Chemical Engineering， Key Laboratory of Material Chemistry for Energy Conversion and Storage， Ministry of Education， Hubei Key Laboratory of Materials Chemistry and Service Failure， Huazhong University of Science and Technology 2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry， College of Chemistry， Jilin University 3. Wuhan National High Magnetic Field Center， Huazhong University of Science and Technology

Received:2026-05-10 Revised:2026-05-28 Online:2026-05-31 Published:2026-05-31
Contact: Hongcheng LU E-mail:yhw1006@hust.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.22422111)

1. ESM to 20260193.pdf(383KB)

Abstract

Abstract: A novel layered magnetic ytterbium coordination compound, Yb(HCOO)(C2O4)(1,10-phen) (1,10-phen = 1,10-phenanthroline), has been successfully synthesized via a solvothermal method. Its crystal structure and magnetic properties were characterized by X-ray diffraction, infrared spectroscopy, thermogravimetric analysis, and magnetic susceptibility measurements. Single-crystal structure analysis reveals that the magnetic Yb3+ ions are connected by formate and oxalate ligands to form a square magnetic lattice, with adjacent layers separated by 1,10-phen ligands. Magnetic measurements show that the dominate interaction between the Yb3+ ions is antiferromagnetic, and no long-range magnetic order is observed down to 2?K. This study provides a new synthetic strategy for constructing low-dimensional magnetic rare-earth coordination compounds.

Key words: Low-dimensional magnetism, Crystal structure, Ytterbium coordination compound, Solvothermal method

CLC Number:

O614

TrendMD:

ZHAI　Xiaolu, LV　Yun, LI　Hui, HUANG　Keke, WANG　Yanhong, LU　Hongcheng. Construction and Magnetic Properties of Low-Dimensional Ytterbium(III) Coordination Polymers Based on Formate and Oxalate Co-Ligands[J]. Chem. J. Chinese Universities, doi: 10.7503/cjcu20260193.

References

Related Articles 15

[1]	XU Yiming, SHI Yiwei, WANG Xin, ZHU Zhihui, SONG Zhiguo, WANG Min. Green Synthesis of Mono- and Disubstituted Quinazolinones by Multi-site Synergistic Catalysis of Novel Three-dimensional Single-nuclear Zn（II） Complexes [J]. Chem. J. Chinese Universities, 2026, 47(2): 20250225.
[2]	BAI Yize, LIU Ruiduan, LU Qiuran, ZHAO Haiyan. Synthesis， Crystal Structure and Catecholase Activity of Copper（II） Complexes with N，N，N⁃Tridentate Schiff Base Ligand [J]. Chem. J. Chinese Universities, 2024, 45(7): 20240063.
[3]	MAO Dongao, XU Linmeng, BI Yanfeng. Structural Transformation and Luminescence Properties of Terbium-sulfonylcalix［4］arene Mononuclear Complexes [J]. Chem. J. Chinese Universities, 2023, 44(11): 20230107.
[4]	LIU Qingqing, WANG Pu, WANG Yongshuai, ZHAO Man, DONG Huanli. Synthesis and Topochemical Polymerization Study of Naphthalene/perylene Imides Substituted Diacetylene Derivatives [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220091.
[5]	SHI Naike, ZHANG Ya, SANSON Andrea, WANG Lei, CHEN Jun. Uniaxial Negative Thermal Expansion and Mechanism in Zn（NCN） [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220124.
[6]	YUE Shengli, WU Guangbao, LI Xing, LI Kang, HUANG Gaosheng, TANG Yi, ZHOU Huiqiong. Research Progress of Quasi-two-dimensional Perovskite Solar Cells [J]. Chem. J. Chinese Universities, 2021, 42(6): 1648.
[7]	TIAN Xia,YANG Fuqun,YUAN Wei,ZHAO Lei,YAO Lei,ZHEN Xiaoli,HAN Jianrong,LIU Shouxin. Synthesis, Structure and Recognition Properties of Macrocyclic Crown Ethers with Oxadiazole ^† [J]. Chem. J. Chinese Universities, 2020, 41(3): 490.
[8]	LIU Dongmei,SU Yajing,LI Shanshan,XU Qiwei,LI Xia. Transition Metal Coordination Polymers Constructed by 4-(4-Carboxyphenoxy)isophthalic Acid: Synthesis, Crystal Structure, Fluorescence Sensing and Photocatalysis ^† [J]. Chem. J. Chinese Universities, 2020, 41(2): 253.
[9]	QIN Liulei,LIU Yang,GUAN Xiaoqin,ZHENG Xiaoyuan,ZHANG Ziyu,LIU Zunqi. Synthesis and Switchable Dielectric Properties of an Inorganic-organic Hybrid Complex [H₂(DABCO)CuCl₄]·H₂O ^† [J]. Chem. J. Chinese Universities, 2020, 41(1): 70.
[10]	LI Bing,WANG Xuemin,BAI Fengying,LIU Shuqing. Synthesises, Structures and Antibacterial Activities of a Series of Rare Earth Nitrogen Heterocyclic Complexes^† [J]. Chem. J. Chinese Universities, 2019, 40(4): 632.
[11]	WANG Dongmei,LIU Zihua,LI Guanghua,LIU Yunling,LI Chunxia. Synthesis, Structure and Fluorescent Property of Indium-based Bimetallic Metal-organic Frameworks^† [J]. Chem. J. Chinese Universities, 2018, 39(9): 1886.
[12]	TIAN Huan, ZHANG Menglong, WANG Lisha, TONG Bihai, ZHAO Zhuo. Synthesis of 4,13-Dithio Benzene and-18-Crown-6 and Its Selective Extractability on A $g + †$ [J]. Chem. J. Chinese Universities, 2018, 39(6): 1191.
[13]	ZHU Lei,HAN Junyan,CHANG Haizhen,QIU Yuyuan,ZHANG Yanan,PENG Danni,HU Wei,MIAO Shaobin. Different Pathways for the Cyclocondensation Reactions of 1,2-Diamine and 1,2-Diketone^† [J]. Chem. J. Chinese Universities, 2018, 39(12): 2686.
[14]	CHEN Qidan, TANG Junjie, FANG Qianrong. Highly Stable Fluorine Containing Hierarchical Porous Covalent Organic Framework^† [J]. Chem. J. Chinese Universities, 2018, 39(11): 2357.
[15]	LI Zheng, LI Rui, LI Xia. Synthesis, Crystal Structure and Fluorescent Properties of Transition Metal Complexes Constructed with 2-(3'-Carboxyphenoxy)benzoic Acid and N-Donor Ligands^† [J]. Chem. J. Chinese Universities, 2018, 39(11): 2363.

Construction and Magnetic Properties of Low-Dimensional Ytterbium(III) Coordination Polymers Based on Formate and Oxalate Co-Ligands

PDF (PC)

Supplement

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments