Hydrogenation of α-Pinene Catalyzed by Ru Nanoparticles Stabilized by Magnetic Alkali Lignin Amine

doi:10.7503/cjcu20200232

Abstract

Abstract: Alkali lignin amine was prepared by introducing amine into alkali lignin structure via Mannich reaction to improve the stability performance for metal nanoparticles. Then the alkali lignin amine was wrapped around Fe₃O₄ magnetic nucleus by co-precipitation method and used as a carrier to construct Ru metal nanoparticle catalyst for hydrogenation of α-pinene. Elemental analysis(EA), X-ray diffraction(XRD), Fourier transform infrared(FTIR), inductively coupled plasma-atomic emission spectroscopy(ICP-AES), transmission electron microscope(TEM), thermogravimetric analysis(TG), X-ray photoelectron spectroscopy(XPS) and other characterizations showed that except for the benzene ring and oxygen-containing groups in alkali lignin, the introduced amine source had exhibited more efficient stabilization for metal nanoparticles. Fe₃O₄@0.8ALN₁-Ru, with a Ru loading of 1.92 mmol/g and Ru particle size of (2.1±0.5) nm, was found the most active catalyst of α-pinene hydrogenation after the study on catalyst preparation process, lignin type, amine source type and amine content. It exhibited a good catalytic performance with 99.64% conversion of α-pinene and 96.52% selectivity for cis-pinene when it catalyzed 1 mL of α-pinene and 1 MPa H₂ at a dosage of 0.05 g and 70℃ for 2 h. Moreover, it's good reuse stability confirmed by a five-run test, which provides a novel method for the development of high value-added lignin-based catalysts.

Key words: Alkali lignin amine, Nanoparticles, α-Pinene, Hydrogenation

CLC Number:

TrendMD:

CHEN Xiangyun, ZHU Benqiang, YUAN Bing, YU Fengli, XIE Congxia, YU Shitao. Hydrogenation of α-Pinene Catalyzed by Ru Nanoparticles Stabilized by Magnetic Alkali Lignin Amine[J]. Chem. J. Chinese Universities, 2020, 41(8): 1826.

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