Selective Oxidation of Atomically Dispersed Fe-N-C Catalyst Under Mild Conditions †

doi:10.7503/cjcu20200149

Abstract

Abstract:

An atomically dispersed Fe-N-C catalyst prepared by one-pot mechanochemical process was used for selective oxidation of sulfides and secondary alcohols. The results show Fe-N-C catalyst can selectively transform sulfides to sulfoxides under mild conditions without any over-oxidized sulfones. This process has several advantages such as mild reaction conditions, high reaction speed and satisfactory yields. In addition, this catalyst exhibits high catalytic activity in the oxidation of the secondary alcohols to the related ketones with decent yields. As a heterogeneous catalyst, activity of this atomically dispersed Fe-N-C does not significantly decrease after 5 times of circulation.

Key words: Single-atom catalyst, Selective oxidation, Iron-nitrogen-doped carbon, Heterogeneous catalyst

CLC Number:

O643

TrendMD:

XIONG Junyu, WANG Shanshan, XU Yanqing, HU Changwen. Selective Oxidation of Atomically Dispersed Fe-N-C Catalyst Under Mild Conditions ^†[J]. Chem. J. Chinese Universities, 2020, 41(6): 1262.

Figures/Tables 8

References 28

[1]	Qiao B., Wang A., Yang X., Allard L. F., Jiang Z., Cui Y., Liu J., Li J., Zhang T., Nat. Chem., 2011, 3, 634—641 doi: 10.1038/nchem.1095 URL
[2]	Flytzani-Stephanopoulos M., Gates B. C., Annu. Rev. Chem. Biomol. Eng., 2012, 3, 545—574 doi: 10.1146/annurev-chembioeng-062011-080939 URL
[3]	Yang X. F., Wang A., Qiao B., Li J., Liu J., Zhang T., Acc. Chem. Res., 2013, 46, 1740—1748 doi: 10.1021/ar300361m URL
[4]	Zhang H., Liu G., Shi L., Ye J., Adv. Energy Mater., 2018, 8, 1701343 doi: 10.1002/aenm.v8.1 URL
[5]	Zhang J., Zhao Y., Chen C., Huang Y., Dong C., Chen C., Liu R., Wang C., Yan K., Li Y., Wang G., J. Am. Chem. Soc., 2019, 141, 20118—20126 doi: 10.1021/jacs.9b09352 URL
[6]	Jiang Z., Sun W., Shang H., Chen W., Sun T., Li H., Dong J., Zhou J., Li Z., Wang Y., Cao R., Sarangi R., Yang Z., Wan D., Zhang J., Li Y., Energy Environ. Sci., 2019, 12, 3508—3514 doi: 10.1039/C9EE02974E URL
[7]	Huang Z., Gu X., Cao Q., Hu P., Hao J., Li J., Tang X., Angew. Chem. Int. Ed., 2012, 51, 4198—4203 doi: 10.1002/anie.201109065 URL
[8]	Deng D., Chen X., Yu L., Wu X., Liu Q., Liu Y., Yang H., Tian H., Hu Y., Du P., Si R., Wang J., Cui X., Li H., Xiao J., Xu T., Deng J., Yang F., Duchesne P. N., Zhang P., Zhou J., Sun L., Li J., Pan X., Bao X., Sci. Adv., 2015, 1, e1500462 doi: 10.1126/sciadv.1500462 URL
[9]	Fei H., Dong J., Arellano-Jimenez M. J., Kim G., Ye N. D., Samuel E. L. G., Peng Z., Zhu Z., Qin F., Bao J., Yacaman M. J., Ajayan P. M., Chen D., Tour J. M., Nat. Commun., 2015, 6, 8668 doi: 10.1038/ncomms9668 URL
[10]	Ortalan V., Uzun A., Gates B. C., Browning N. D., Nat. Nano, 2010, 5, 506—510 doi: 10.1038/nnano.2010.92 URL
[11]	Lin L., Yang Z. K., Jiang Y. F., Xu A. W., ACS Catal., 2016, 6, 4449—4454 doi: 10.1021/acscatal.6b00535 URL
[12]	Wang Y. C., Lai Y. J., Song L., Zhou Z. Y., Liu J. G., Wang Q., Yang X. D., Chen C., Shi W., Zheng Y. P., Rauf M., Sun S. G., Angew. Chem. Int. Ed., 2015, 54, 9907—9910 doi: 10.1002/anie.201503159 URL
[13]	Wu G., More K. L., Johnston C. M., Zelenay P., Science, 2011, 332, 443—447 doi: 10.1126/science.1200832 URL
[14]	Zhao Y., Watanabe K., Hashimoto K., J. Am. Chem. Soc., 2012, 134, 19528—19531 doi: 10.1021/ja3085934 URL
[15]	Wei W., Shi X., Gao P., Wang S., Hu W., Zhao X., Ni Y., Xu X., Xu Y., Yan W., Ji H., Cao M., Nano Energy, 2018, 52, 29—37 doi: 10.1016/j.nanoen.2018.07.033 URL
[16]	Huan T. N., Ranjbar N., Rousse G., Sougrati M., Zitolo A., Mougel V., Jaouen F., Fontecave M., ACS Catal., 2017, 7, 1520—1525 doi: 10.1021/acscatal.6b03353 URL
[17]	Gu J., Hsu C. S., Bai L., Chen H. M., Hu X., Science, 2019, 364, 1091—1094 doi: 10.1126/science.aaw7515 URL
[18]	Pan F., Zhang H., Liu K., Cullen D., More K., Wang M., Feng Z., Wang G., Wu G., Li Y., ACS Catal., 2018, 8, 3116—3122 doi: 10.1021/acscatal.8b00398 URL
[19]	Liu W., Zhang L., Liu X., Liu X., Yang X., Miao S., Wang W., Wang A., Zhang T., J. Am. Chem. Soc., 2017, 139, 10790—10798 doi: 10.1021/jacs.7b05130 URL
[20]	Zhang M., Wang Y. G., Chen W., Dong J., Zheng L., Luo J., Wan J., Tian S., Cheong W. C., Wang D., Li Y., J. Am. Chem. Soc., 2017, 139, 10976—10979 doi: 10.1021/jacs.7b05372 URL
[21]	Zhang J., Nagamatsu S., Du J., Tong C., Fang H., Deng D., Liu X., Asakura K., Yuan Y., J. Catal., 2018, 367, 16—26 doi: 10.1016/j.jcat.2018.08.004 URL
[22]	Boruah J. J., Ahmed K., Das S., Gogoi S. R., Saikia G., Sharma M., Islam N. S., J. Mol. Catal. A-Chem., 2016, 425, 21—30 doi: 10.1016/j.molcata.2016.09.026 URL
[23]	Mirfakhraei S., Hekmati M., Eshbala F. H., Veisi H., New J. Chem., 2018, 42, 1757—1761 doi: 10.1039/C7NJ02513K URL
[24]	Fareghi-Alamdari R., Zekri N., Moghadam A. J., Farsani M. R., Catal. Commun., 2017, 98, 71—75 doi: 10.1016/j.catcom.2017.04.050 URL
[25]	Rostamnia S., Gholipour B., Liu X., Wang Y., Arandiyan H., J. Colloid Interface Sci., 2018, 511, 447—455 doi: 10.1016/j.jcis.2017.10.028 URL
[26]	Allahresani A., Nasseri M. A., RSC Adv., 2014, 4, 60702—60710 doi: 10.1039/C4RA09973G URL
[27]	Védrine J., Catalysts, 2017, 7, 341 doi: 10.3390/catal7110341 URL
[28]	Rajabi F., Naserian S., Primo A., Luque R., Adv. Synth. Catal., 2011, 353, 2060—2066 doi: 10.1002/adsc.201100149 URL