Synthesis and Characterization of a 3D Coordination Polymer with Heterometallic Chains and Honeycombed Nanochannels†

doi:10.7503/cjcu20170004

Abstract

Abstract:

Using 5-(hydroxymethyl)isophthalic acid(H₂HIA) as the ligand to assemble with Zn²⁺ ion and K⁺ ion, an open 3D coordination polymer named [Zn_0.5K_0.5(HIA)(H₂O)]·xGuest(1) was constructed under solvothermal conditions. Complex 1 contains interesting infinite hetrometallic chains and honeycombed nanochannels. Powder X-ray diffraction(PXRD) and thermogravimetry analyses(TGA) techniques were applied to characterizing complex 1 and the photoluminescent properties of complex 1 were also investigated.

Key words: 5-(Hydroxymethyl)isophthalic acid, Hetrometallic chain, Honeycombed nanochannel

CLC Number:

O614.2

TrendMD:

XU Zhongxuan, LÜ Guoling. Synthesis and Characterization of a 3D Coordination Polymer with Heterometallic Chains and Honeycombed Nanochannels^†[J]. Chem. J. Chinese Universities, 2017, 38(9): 1531.

Figures/Tables 7

Scheme 1 Synthetic route for ligand H2HIA

Table 1 Crystal data and refinement results for complex 1

Complex	1	Temperature/K	293(2)
Chemical formula	C₉H_5.78K_0.50O_6.08Zn_0.50	Z	36
Formula weight	263.48	Radiation type	Mo Kα
Crystal system	Hexagonal	Absorption coefficient, μ/mm^-1	1.105
Space group	R $3 ˉ$ c	Number of reflections measured	9518
a/nm	2.96075(9)	Number of independent reflections	2938
b/nm	2.96075(9)	R_int	0.0243
c/nm	1.61371(6)	Final R₁/wR(F²)[(I>2σ(I)]	0.0848/0.2971
α/(°)	90.00	Final R₁(all data)	0.0947
β/(°)	90.00	Goodness of fit on F²	1.048
γ/(°)	120.00	CCDC No.	1525258
Unit cell volume/nm³	12.2507(7)

Table 1 Crystal data and refinement results for complex 1

Complex	1	Temperature/K	293(2)
Chemical formula	C₉H_5.78K_0.50O_6.08Zn_0.50	Z	36
Formula weight	263.48	Radiation type	Mo Kα
Crystal system	Hexagonal	Absorption coefficient, μ/mm^-1	1.105
Space group	R $3 ˉ$ c	Number of reflections measured	9518
a/nm	2.96075(9)	Number of independent reflections	2938
b/nm	2.96075(9)	R_int	0.0243
c/nm	1.61371(6)	Final R₁/wR(F²)[(I>2σ(I)]	0.0848/0.2971
α/(°)	90.00	Final R₁(all data)	0.0947
β/(°)	90.00	Goodness of fit on F²	1.048
γ/(°)	120.00	CCDC No.	1525258
Unit cell volume/nm³	12.2507(7)

Fig.1 Coordination environment of ligand HIA2-in complex 1Symmetry codes: a. x-y, x, -z; b. 1/3-x, 2/3-y, 1/3-z.

Fig.2 Infinite hetrometallic chain(A) and honeycombed nanochannels(B) in complex 1Oxygen atoms of —CH2OH groups are shown in blue.

Fig.3 Framework of complex 1 constructed by hexagonal channels

Fig.4 PXRD pattern(A) and TGA curve(B) of complex 1

Fig.5 Fluorescent emission spectra of ligand H2HIA(a) and complex 1(b) in the solid state at room temperature

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