Long Chain Bismaleimide Modified Cyanate Ester Resin and Its Composites

doi:10.7503/cjcu20130281

Chem. J. Chinese Universities ›› 2013, Vol. 34 ›› Issue (8): 1979.doi: 10.7503/cjcu20130281

• Polymer Chemistry • Previous Articles Next Articles

Long Chain Bismaleimide Modified Cyanate Ester Resin and Its Composites

MA Peng-Chang¹, LIU Jing-Feng², FAN Wei-Feng², MENG Xiang-Sheng², YANG Ming³

1. Department of Chemical Engineering, Zhongshan Polytechnic, Zhongshan 528404, China;
2. The Engineering Center of Polymer Composite, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;
3. Beijing Institute of Aerospace Material, Beijing 100095, China

Received:2013-03-26 Online:2013-08-10 Published:2013-07-19
Contact: Ming Yang E-mail:ym_3006@hotmail.com;austin@ciac.jl.cn

Abstract

Abstract:

A kind of long chain bismaleimide-modified cyanate ester resin and the relevant composites were prepared and characterized. The results indicate that when the resin content of the long chain maleimide-terminated thioetherimide(MIMTI) reached 37.5%(mass fraction), the T_5%of the modified cyanate ester resin(MTI/T₃) was 414℃. Tensile strength and flexural strength of the MTI/T₃ composite were 431.2 and 331.0 MPa, 631.5 and 278.4 MPa at room temperature and 200℃, respectively. And its coefficient of thermal expansion(CTE) in X-Y axis and the moisture absorption were 18.1×10^-6℃^-1 and 1.4%, respectively. Compared to the common bismaleimide-modified cyanate ester resins, and the 20% and 30% MIMTI-modified cyanate ester resin MTI/T₁ and MTI/T₂, respectively, the obtained cyanate ester resin MTI/T₃ exhibited good processing, excellent heat resistance and mechanical properties, low moisture absorption and low CTE.

Key words: Cyanate ester, Bismaleimide, Mechanical property, Coefficient of thermal expansion(CTE), Moisture absorption

CLC Number:

O631
TQ323

TrendMD:

MA Peng-Chang, LIU Jing-Feng, FAN Wei-Feng, MENG Xiang-Sheng, YANG Ming. Long Chain Bismaleimide Modified Cyanate Ester Resin and Its Composites[J]. Chem. J. Chinese Universities, 2013, 34(8): 1979.

[1]	LUO Xinyan, JIA Ruonan, XIANG Yong, ZHANG Xiaokun. Progress on the Stretchable Composite Solid Polymer Electrolytes [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220149.
[2]	LI Qiao, ZHAO Yang, WANG Enju. Moisture Absorption Reaction and Fluorescence Property of Highly Active Michael System Based on Arylidenemalononitrile [J]. Chem. J. Chinese Universities, 2022, 43(3): 20210690.
[3]	ZHANG Zhibo, SHANG Han, XU Wenxuan, HAN Guangdong, CUI Jinsheng, YANG Haoran, LI Ruixin, ZHANG Shenghui, XU Huan. Self-Assembly of Graphene Oxide at Poly（3-hydroxybutyrate） Microparticles Toward High-performance Intercalated Nanocomposites [J]. Chem. J. Chinese Universities, 2022, 43(2): 20210566.
[4]	XU Huan, KE Lyu, TANG Mengke, SHANG Han, XU Wenxuan, ZHANG Zilin, FU Yanan, HAN Guangdong, CUI Jinsheng, YANG Haoran, GAO Jiefeng, ZHANG Shenghui, HE Xinjian. In⁃situ Liquid Exfoliation of Montmorillonite Nanosheets in Poly（lactic acid） to Resist Oxygen Permeation [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220316.
[5]	WANG Xianwei, KE Hongjun, YUAN Hang, LU Gewu, LI Liying, MENG Xiangsheng, SONG Shulin, WANG Zhen. High Temperature Resistant and Soluble Polyimide Resins and Their Composites [J]. Chem. J. Chinese Universities, 2021, 42(6): 2041.
[6]	WANG Peng, MAO Dan, WAN Jiawei, QI Qi, DU Jiang, WANG Dan. Effect of Hollow Multi-shelled TiO₂ on Mechanical Properties of Epoxy Resin Composites [J]. Chem. J. Chinese Universities, 2021, 42(10): 3218.
[7]	SHA Di, YU Xumin, ZHAO Jiang, MA Xiaofei, WANG Hanfu, LIU Fangfang, QIU Xuepeng. Preparation and Mechanical Properties of Carbon Fiber Triaxial Woven Fabric/Epoxy Composites ^† [J]. Chem. J. Chinese Universities, 2020, 41(4): 838.
[8]	SUI Jiayang, LIU Xiaoyang, QIAN Miaomiao, ZHU Yanchao, XUE Beichen, FENG Yi, TIAN Yumei, WANG Xiaofeng. Surface Modification of Silica/carbon Black Derived from Rice Husks and Its Influence on Natural Rubber Composites^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1561.
[9]	LIU Tao,LI Wenjing,ZHANG Enshuang,ZHONG Jinyang,ZHANG Fan,LIU Yuanyuan,ZHAO Yingmin. Preparation and Properties of Flexible Cross-linked Polyimide Aerogels [J]. Chem. J. Chinese Universities, 2019, 40(2): 403.
[10]	YE Longqiang,KANG Shuo,ZHANG Weihao,ZHANG Yulu,HUI Zhenzhen,JIANG Bo. Sol-gel Preparation of Anti-Fogging SiO₂/SiO₂-TiO₂ Double-layer Antireflective Coating ^† [J]. Chem. J. Chinese Universities, 2019, 40(11): 2274.
[11]	GAO Feilong, LI Yongcun, LUAN Yunbo, XUE Zhicheng, GUO Zhangxin, ZHANG Qi, WU Guiying. Enhancement Mechanisms of Mechanical and Self-Healing Properties of Thermoplastic Polyurethane Composites Induced by Different G-CNT Hybridization Systems^† [J]. Chem. J. Chinese Universities, 2018, 39(4): 832.
[12]	LU Lingang,CHENG Zhe,QIU Xinming,WANG Huiya,YANG Shousheng,QIAN Xiaodong,WANG Xuebao. Preparation of Green Star-topology Phosphazene Flame Retardant and Properties of Flame-retardant Epoxy Resin^† [J]. Chem. J. Chinese Universities, 2018, 39(12): 2789.
[13]	LIU Yu,CHEN Gang,ZHU Jiatian,CHEN Wenjin,HU Wen,LIU Yingyao,FANG Zhiqiang. Preparation, Structure and Properties of Strong, Transparent Cellulose Materials^† [J]. Chem. J. Chinese Universities, 2018, 39(10): 2298.
[14]	WANG Zhiwei, HUANG Di, XI Shaohui, XU Mengjie, ZHU Xuefang, LIAN Xiaojie, WEI Yan, CHEN Weiyi. Cell Response and Mechanical Properties of the Nanofibers Reinforced Bilayered Tissue Guided Memberanes^† [J]. Chem. J. Chinese Universities, 2018, 39(1): 178.
[15]	LÜ Xiujuan, SONG Yu, ZHANG Wenke. Single Molecule Force Spectroscopy Study on the Apparent Nanomechanical Properties of Polyethylene Single Crystals^† [J]. Chem. J. Chinese Universities, 2018, 39(1): 166.

Long Chain Bismaleimide Modified Cyanate Ester Resin and Its Composites

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments