Preparation of Metalloporphyrin with Disulfide Bond and Electrocatalytic Reduction of Oxygen

doi:10.7503/cjcu20120803

Abstract

Abstract:

A novel amino acid derivatised mesoporphyrin Co(Ⅱ)-[2,7,12,18-tetramethyl-3,8-diethyl-13,17-(propionylaminoethyl-dithio-ethyaminoformylethyl)-29, 34-bis-(methoxy-formyl)]-prophyrin[Co(Ⅱ)MPDTEP, Ⅴ] was prepared from hemin by a six-steps reaction including deferrization, esterification, cataly-tic hydrogenation, hydrolyzation, condensation and complexation. The target products were characterized. The effects of the reaction time and temperature on the yields of the product [2,7,12,18-tetramethyl-3,8-diethyl-13,17-(propionylaminoethyl-dithio-ethyaminoformylethyl)-29,34-bis-(methoxy-formyl)]-prophyrin(MPDTEP, Ⅳ) were investigated. A gold electrode modified by Co(Ⅱ)MPDTEP was prepared by self-assembly of disulfide on gold. The properties of the modified electrode were investigated by FTIR as well as electrochemical methods. This modified electrode was successfully used for the electrocatalytic reduction of oxygen.

Key words: Hemin, Porphyrin, Self-assembly, Modified electrode, Electrocatalytic reduction

CLC Number:

O646
O626

TrendMD:

HUANG Xiu-You, HU Bing-Cheng, XU Shi-Chao. Preparation of Metalloporphyrin with Disulfide Bond and Electrocatalytic Reduction of Oxygen[J]. Chem. J. Chinese Universities, 2013, 34(6): 1510.

[1]	LI Lin, QI Fenglian, QIU Lili, MENG Zihui. Dynamic Amorphous Photonic Structure Patterns Assembled by Hexagonal Magnetic Nanosheets [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220123.
[2]	WU Yushuai, SHANG Yingxu, JIANG Qiao, DING Baoquan. Research Progress of Controllable Self-assembled DNA Origami Structure as Drug Carrier [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220179.
[3]	QIU Liqi, YAO Xiangyang, HE Liangnian. Visible-light-driven Selective Reduction of Carbon Dioxide Catalyzed by Earth-abundant Metalloporphyrin Complexes [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220064.
[4]	YU Bin, CHEN Xiaoyan, ZHAO Yue, CHEN Weichang, XIAO Xinyan, LIU Haiyang. Graphene Oxide-based Cobalt Porphyrin Composites for Electrocatalytic Hydrogen Evolution Reaction [J]. Chem. J. Chinese Universities, 2022, 43(2): 20210549.
[5]	LI Bo, MENG Yuxi, WANG Wenwen, ZANG Hongying. Synthesis and Proton Conductivity of Polynuclear Polyoxothiomolybdate Compound [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210657.
[6]	DU Shunfu, WANG Wenjing, EL⁃SAYED El⁃Sayed M., SU Kongzhao, YUAN Daqiang, HONG Maochun. A Chemiluminescent Zirconocene Coordination Tetrahedron [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210628.
[7]	XUE Jin, CAO Xiaowei, LIU Yifan, WANG Min. Preparation of Paper Hollow Gold Nanocage SERS Sensor and Its Rapid and Highly Sensitive Detection for miRNAs in Sputum of Patients with Non-small Cell Lung Cancer [J]. Chem. J. Chinese Universities, 2021, 42(8): 2393.
[8]	ZHU Qichen, XIONG Ming, TAO Siyu, TANG Siwei, REN Qizhi. Effect of Light Source on the Photocatalytic Performance of Dihydroxynaphthalene by Water-soluble Sulfonated Porphyrins [J]. Chem. J. Chinese Universities, 2021, 42(6): 1933.
[9]	MA Zihui, WANG Mengyan, CAO Hongyu, TANG Qian, WANG Lihao, ZHENG Xuefang. Transient Absorption and Decay Kinetic Properties of Photo-excited Metal Coordinated Tetraphenylporphyrin [J]. Chem. J. Chinese Universities, 2021, 42(3): 767.
[10]	ZHANG Juan, HU Xinyue, WANG Hongbo, LIAN Ying, LE Jinyu, YANG Zihao. Crystal-like Hydrogels Consisting of Parallel Hexahedrons Obtained from the Self-assembly ofβ⁃Cyclodextrin/perfluorononanoic Acid Inclusion Complexes [J]. Chem. J. Chinese Universities, 2021, 42(10): 3187.
[11]	TANG Wentao, LI Shengkai, WANG Shen, CHEN Long, CHEN Zhuo. Laser-mediated Enrichment Based Surface Enhanced Raman Analysis [J]. Chem. J. Chinese Universities, 2021, 42(10): 3054.
[12]	XIE Xingyu, ZHAO Yaxiang, ZHAO Lizhi, LI Rishun, WU Dihao, YE Hui, XIN Qingping, LI Hong, ZHANG Yuzhong. Colorimetric Detection Method for H₂O₂ Based on Two-dimensional Metal-organic Frameworks of Metalloporphyrin [J]. Chem. J. Chinese Universities, 2020, 41(8): 1776.
[13]	HOU Chunxi, LI Yijia, WANG Tingting, LIU Shengda, YAN Tengfei, LIU Junqiu. Application of Elastin-like Polypeptides in Supramolecular Assembly ^† [J]. Chem. J. Chinese Universities, 2020, 41(6): 1163.
[14]	BAI Ruonan, LI Qing, QIAO Shanlin, ZHANG Chunhuan, ZHAO Yongsheng. Controlled Preparation and Optical Waveguide Property of 1,4-Dicarbazolidinylbenzene Microwires ^† [J]. Chem. J. Chinese Universities, 2020, 41(5): 967.
[15]	WANG Jun, WANG Tie. Recent Progress in Functional Nanomaterials Based on Self-assembly Technology ^† [J]. Chem. J. Chinese Universities, 2020, 41(3): 377.

Preparation of Metalloporphyrin with Disulfide Bond and Electrocatalytic Reduction of Oxygen

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments