高等学校化学学报

高等学校化学学报

• 研究论文 • 上一篇    下一篇

溶剂热法直接合成酞菁铜晶体

夏道成1, 于书坤2, 马春雨1, 程传辉1,2, 郭振强2, 纪冬梅2, 范昭奇1,2, 杜锡光4, 王旭3, 杜国同1,2   

    1. 大连理工大学三束材料改性国家重点实验室, 物理与光电工程学院, 大连 116023;
    2. 吉林大学集成光电子国家重点实验室, 电子科学与工程学院,
    3. 吉林大学超分子结构与材料国家重点实验室, 长春 130012;
    4. 东北师范大学化学学院, 长春 130024
  • 收稿日期:2007-06-18 修回日期:1900-01-01 出版日期:2008-02-10 发布日期:2008-02-10
  • 通讯作者: 杜国同

Directly Solvothermal Synthesis of Copper Phthalocyanine Crystals

XIA Dao-Cheng1, YU Shu-Kun2, MA Chun-Yu1, CHENG Chuan-Hui1,2, GUO Zhen-Qiang2, JI Dong-Mei2, FAN Zhao-Qi1,2, DU Xi-Guang4, WANG Xu3, DU Guo-Tong1,2*   

    1. State Key Laboratory of Materials Modification by Laser, Ion and Electron Beams, School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116023, China;
    2. State Key Laboratory on Integrated Optoelectronics, College of Electronic Science & Engineering,
    3. State Key Laboratory of Superamolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, China;
    4. Faculty of Chemistry, Northeast Normal University, Changchun 130024, China
  • Received:2007-06-18 Revised:1900-01-01 Online:2008-02-10 Published:2008-02-10
  • Contact: DU Guo-Tong

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被引次数

14

摘要： 以喹啉为溶剂, 在反应釜中将1,3-二异吲哚、钼酸铵和二水乙酸铜在喹啉中反应, 降至室温后得到长10.5 mm针状的酞菁铜单晶, 最佳的反应条件: 以10 mL喹啉为溶剂, 于270 ℃反应8 h, 产率为51.3%.

关键词: 溶剂热合成, 酞菁铜, 单晶, 喹啉

Abstract: A novel method for directly synthesizing β-form crystals of copper phthalocyanine(CuPc) was pre-sented in this article. With quinoline as a solvent, crystals were grown after cooling the reaction mixture to room temperature in an autoclave which contains 1,3-diiminoisoindoline, NH4MoO4 and Cu(AcO)2·2H2O in quinoline solvent. These high quality crystals were suitable for characterization measurements. Needle-like single crystals of CuPc with a size up to 10.5 mm in length were obtained. The influences of different temperatures and times on the crystal yields were also discussed. The optimum reaction condition of the crystal growth was as follows: reaction temperature was 270 ℃, the reaction time was 8 h, and the reaction solvent volume was 10 mL, and the highest crystal yield was 51.3%. This method is called solvothermal synthesis method. Moreover, this method may be easily applied in the crystal growth for other organic functional raw materials, and acts as an important part both in scientific experiments and industrial productions.

Key words: Solvothermal synthesis, CuPc, Single crystal, Quinoline

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