高等学校化学学报

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (6): 942.

• 论文 • 上一篇    下一篇

RECl3与丝氨酸配合行为的研究

李仲谨1, 冀棉2, 刘建睿2, 高胜利2   

  1. 1. 西北轻工业学院化工系, 咸阳, 712081;
    2. 西北大学化学系, 西安, 710069
  • 收稿日期:1998-01-22 出版日期:1998-06-24 发布日期:1998-06-24
  • 通讯作者: 李仲谨,男,51岁,副教授.
  • 作者简介:李仲谨,男,51岁,副教授.
  • 基金资助:

    陕西省自然科学基金

A Study of Coordination Behaviour of RECl3 with Serine

LI Zhong-Jin1, JI Mian2, LIU Jian-Rui2, GAO Sheng-Li2   

  1. 1. Department of Chemical Engineering, Northwest Institute of Light Industry, Xianyang, 712081;
    2. Department of Chemistry, Northwest University, Xi′an, 710069
  • Received:1998-01-22 Online:1998-06-24 Published:1998-06-24

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摘要： 依据相平衡结果,于水中合成了RE(Ser)Cl3·3H2O和RE(Ser)2Cl3·5H2O(RE=La-Nd,Sm-Gd,Dy,Yb,Y)等20种固态配合物,利用化学分析、摩尔电导、IR、UV、FS、X射线衍射分析及TG-DTG等手段对配合物进行了表征.

关键词: 稀土氯化物, 丝氨酸, 固态配合物, 表征

Abstract: Under the guide of phase equilibrium results, 20 solid complexes RE(Ser)Cl3·3H2O and RE(Ser)2Cl3·5H2O(RE=La—Nd, Sm—Gd, Dy, Yb, Y) have been prepared in water, and characterized by chemical analysis, molar conductivity, IR, UV, FS, X-ray diffraction and TG-DTG.

Key words: Rare earth chloride, Serine, Solid complex, Characterization

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