高等学校化学学报 ›› 2021, Vol. 42 ›› Issue (4): 1031.doi: 10.7503/cjcu20200620
收稿日期:
2020-08-31
出版日期:
2021-04-10
发布日期:
2020-12-15
通讯作者:
汪大洋
E-mail:wangdayang@jlu.edu.cn
基金资助:
Received:
2020-08-31
Online:
2021-04-10
Published:
2020-12-15
Contact:
WANG Dayang
E-mail:wangdayang@jlu.edu.cn
Supported by:
摘要:
立足于分子自组装单层膜的制备及结构, 讨论了分子自组装单层膜的头基基团与基底的作用机理、 主链与环境的温度依赖关系, 特别是其端基基团的化学性质及构象对表面浸润行为的影响. 重点讨论了分子自组装单层膜的端甲基基团对表面能的贡献、 极性端基基团与水分子之间的相互作用以及自组装单层膜表面的分子尺寸粗糙度对表面浸润的影响. 最后, 基于理论和实验基础对以上问题提出新的认知与看法, 并对未来该领域发展的机遇与挑战进行了展望.
中图分类号:
TrendMD:
马卓远, 汪大洋. 分子自组装单层膜的表面浸润性研究现状和展望. 高等学校化学学报, 2021, 42(4): 1031.
MA Zhuoyuan, WANG Dayang. Status and Prospect of Surface Wettability of Molecular Self-assembled Monolayers. Chem. J. Chinese Universities, 2021, 42(4): 1031.
Fig.1 Schematic diagram of an ideal, single?crystalline SAM of alkanethiolates supported on a gold surface with a (111) texture[13]Copyright 2005, American Chemical Society.
Polymer | Structureal formula | γc/(mJ·m-2) |
---|---|---|
Poly(vinylidene chloride) | —(CH2CCl2)n— | 40 |
Poly(vinyl chloride) | —(CH2CHCl)n— | 39 |
Polyethylene | —(CH2)n— | 31 |
Poly(vinyl fluoride) | —(CH2CHF)n— | 28 |
Poly(vinylidene fluoride) | —(CH2CF2)n— | 25 |
Polytrifluoroethylene | —(CH2CHF)n— | 22 |
Polytetrafluoroethylene | —(CF2)n— | 18 |
—CH3(crystal) | —CH3 | 22 |
—CH3(monolayer) | —CH3 | 24 |
—CF3(monolayer) | —CF3 | 6 |
Polystyrene | —(CH2CHC6H6)n— | 33 |
Poly(methyl methacrylate) | —(CH2CH3COOCCH3)n— | 39 |
Table 1 Relationship between wettability and surface structure[59]*
Polymer | Structureal formula | γc/(mJ·m-2) |
---|---|---|
Poly(vinylidene chloride) | —(CH2CCl2)n— | 40 |
Poly(vinyl chloride) | —(CH2CHCl)n— | 39 |
Polyethylene | —(CH2)n— | 31 |
Poly(vinyl fluoride) | —(CH2CHF)n— | 28 |
Poly(vinylidene fluoride) | —(CH2CF2)n— | 25 |
Polytrifluoroethylene | —(CH2CHF)n— | 22 |
Polytetrafluoroethylene | —(CF2)n— | 18 |
—CH3(crystal) | —CH3 | 22 |
—CH3(monolayer) | —CH3 | 24 |
—CF3(monolayer) | —CF3 | 6 |
Polystyrene | —(CH2CHC6H6)n— | 33 |
Poly(methyl methacrylate) | —(CH2CH3COOCCH3)n— | 39 |
Fig.2 A strip of one?dimensional water chain in carbon nano tube(A)[74]; a layer of two?dimension “ice?like” water on graphene surface(B)[78]; a ball of three?dimensional water in inorganic cage material(C)[79](A) Copyright 2010, American Physical Society; (B) Copyright 2016, Elsevier; (C) Copyright 2012, Wiley-VCH.
Fig.3 Desorption experiment of surface water with different tail groups(A)[82] and residual interface water after external dehydration with different tail groups(B)[83](A) Copyright 2008, American Chemical Society; (B) Copyright 2019, American Chemical Society.
Fig.4 Composite structure of carboxyl self?assembled monolayers(A)[85]; the strong hydrogen bonding between water molecules(B)[86]; the relationgship of contact Angle and chain density on carboxyl self?assembled monolayers(C)[87]; surface plasmon resonance absorption of fibrous protein(black) and bovine serum albumin(red) with chain density curves(D)[92](A) Copyright 2011, Royal Society of Chemistry; (B) Copyright 2004, American Association for the Advancement of Science; (C) Copyright 2015, American Chemical Society; (D) Copyright 2004, American Chemical Society.
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