三维多孔锌钨氧化物异质结的制备、组分调控与光催化性能

doi:10.7503/cjcu20190286

高等学校化学学报 ›› 2019, Vol. 40 ›› Issue (11): 2367.doi: 10.7503/cjcu20190286

三维多孔锌钨氧化物异质结的制备、组分调控与光催化性能

刘美宏,陶然,李冰,李兴华(),韩朝翰,李晓伟,邵长路()

东北师范大学物理学院, 先进光电子功能材料研究中心, 紫外光发射材料与技术教育部重点实验室, 长春 130024

收稿日期:2019-05-20 出版日期:2019-11-10 发布日期:2019-09-05
通讯作者: 李兴华,邵长路 E-mail:lixh781@nenu.edu.cn;clshao@nenu.edu.cn
基金资助:
国家自然科学基金资助(51572045);国家自然科学基金资助(51732003);国家自然科学基金资助(61803080);国家自然科学基金资助(91233204)

Controllable Preparation and Photocatalytic Properties of Three-dimensional Porous Zinc-tungsten Oxide Heterojunctions ^†

LIU Meihong,TAO Ran,LI Bing,LI Xinghua(),HAN Chaohan,LI Xiaowei,SHAO Changlu()

School of Physics, Center for Advanced Optoelectronic Functional Materials Research, Key Laboratory of UV Light-Emitting Materials and Technology of Ministry of Education, Northeast Normal University, Changchun 130024, China

Received:2019-05-20 Online:2019-11-10 Published:2019-09-05
Contact: LI Xinghua,SHAO Changlu E-mail:lixh781@nenu.edu.cn;clshao@nenu.edu.cn
Supported by:
? Supported by the National Natural Science Foundation of China(51572045);Supported by the National Natural Science Foundation of China(51732003);Supported by the National Natural Science Foundation of China(61803080);Supported by the National Natural Science Foundation of China(91233204)

摘要/Abstract

摘要：

采用真空冷冻干燥技术, 通过调控前驱体溶液的组成, 实现了锌钨氧化物异质结材料的可控制备. 前驱物中高分子的引入使煅烧后的氧化物材料很好地保持了三维连通的多孔结构. 光催化实验结果表明, 获得的系列材料均能够实现对罗丹明B的脱色降解, 并表现出组分依赖的光催化活性. 氧化锌/钨酸锌三维多孔异质结材料相比于其它样品具有更高的光催化活性, 可在180 min内将罗丹明B完全脱色.

关键词: 真空冷冻干燥, 三维多孔材料, 锌钨氧化物, 异质结, 光催化, 罗丹明B

Abstract:

The zinc and tungsten oxides and their heterojunctions were controllably prepared by adjusting the precursor compositions using a vacuum freeze-drying technology. Owing to the introduction of a polymer in the precursor, the calcined oxide materials could maintain their three-dimensional connected porous structures. The photocatalytic experiments showed that the obtained series of materials could achieve the decolorization degradation of Rhodamine B and exhibit component-dependent photocatalytic activity. The zinc oxide/zinc tungstate three-dimensional porous heterojunctions showed higher photocatalytic activity than the other samples, which could completely decolorize Rhodamine B within 180 min.

Key words: Vacuum freeze-drying, Three-dimensional porous material, Zinc-tungsten oxide, Hetero-structure, Photocatalysis, Rhodamine B

中图分类号:

O643.3

TrendMD:

刘美宏, 陶然, 李冰, 李兴华, 韩朝翰, 李晓伟, 邵长路. 三维多孔锌钨氧化物异质结的制备、组分调控与光催化性能. 高等学校化学学报, 2019, 40(11): 2367.

LIU Meihong, TAO Ran, LI Bing, LI Xinghua, HAN Chaohan, LI Xiaowei, SHAO Changlu. Controllable Preparation and Photocatalytic Properties of Three-dimensional Porous Zinc-tungsten Oxide Heterojunctions ^†. Chem. J. Chinese Universities, 2019, 40(11): 2367.

图/表 12

Fig.1 XRD patterns of WO3, WO3/ZnWO4, ZnWO4, ZnO/ZnWO4 and ZnO

Fig.2 SEM images of WO3/ZnWO4(A, B) and ZnO/ZnWO4(C, D) before(A, C) and after(B, D) heat treatment

Fig.3 TEM(A) and corresponding HRTEM(B) images of WO3/ZnWO4, TEM(C) and corresponding HRTEM(D) images of ZnO/ZnWO4

Fig.4 TG curves of the samples before heat treatment

Fig.5 N2 adsorption-desorption isotherm and pore-size distributions(insets) of WO3(A), WO3/ZnWO4(B), ZnWO4(C), ZnO/ZnWO4(D), ZnO(E) and specific surface area of the samples(F) a. Adsorption; b. desorption.

Fig.6 XPS spectra of WO3, WO3/ZnWO4, ZnWO4, ZnO/ZnWO4 and ZnO (A) Full spectrum; (B) Z n 2 p core level; (C) W 4 f core level.

Fig.7 UV-Vis absorption spectra of WO3, WO3/ZnWO4, ZnWO4, ZnO/ZnWO4 and ZnO

Fig.8 Photocurrent spectra(A) and PL spectra(B) of WO3, WO3/ZnWO4, ZnWO4, ZnO/ZnWO4 and ZnO

Fig.9 Photocatalytic degradation of RhB with different samples under simulated sunlight

Fig.10 Effects of scavengers for photodegradation of RhB with WO3/ZnWO4(A) and ZnO/ZnWO4(C) under simulated sunlight and ESR spectra of DMPO-·O2- and DMPO-·OH with WO3/ZnWO4(B) and ZnO/ZnWO4(D) before and after simulated sunlight irradiation

Fig.11 Schematic diagram of the energy band positions of zinc-tungsten oxides

Fig.12 Degradation cycling test of RhB with ZnO/ZnWO4 under simulated sunlight

参考文献 24

[1]	Frank S. N., Bard A. J., J. Am. Chem. Soc., 1977,99(1), 303— 304
[2]	Frank S. N., Bard A. J., J. Phys. Chem., 1977,81(15), 1484— 1488
[3]	Wang H., Li G., Jia L., Wang G., Tang C ., J. Phys. Chem. C, 2008,112(31), 11738— 11743
[4]	Asahi R., Morikawa T., Ohwki T ., Science, 2001,293(5528), 269— 271
[5]	Zhang L. S., Wang W.Z., Zhou L., Xu H.L., Small, 2007,3(9), 1618— 1625
[6]	Zhang Z., Shao C., Li X., Zhang M., Liu Y., ACS Appl. Mater. Interfaces, 2010,2(10), 2915— 2923
[7]	Lu F., Cai W., Zhang Y., Adv. Funct. Mater., 2008,18(7), 1047— 1056
[8]	Rashid M. H., Paira T. K., Dinda E., Mandal T. K., Raula M., Langmuir, 2010,26(11), 8769— 8782
[9]	Lai Y., Meng M., Yu Y., Appl.Catal. B: Environ., 2010,100(3/4), 491— 501
[10]	Sun W., Li X. H., Shao C. L., Li X. W., Zhao L., Lu N., J. Mater. Sci-Mater. El., 2018,29, 9605— 9612
[11]	Li X. W., Zhao L., Shao C. L., Li X. H., Sun W., Liu Y. C., J. Colloid Interf. Sci., 2018,530, 345— 352
[12]	Li B., Li X. W., Shao C. L., Li X. H., Liu H. Y., Yang S., Tao R., Liu Y. C., Ind. Eng. Chem. Res., 2019,58, 14106— 14114
[13]	Jiang Z. Y., Liu Y. Y., Jing T., Huang B. B., Wang Z. Y., Zhang X. Y., Qin X. Y., Dai Y., Appl. Catal. B: Environ., 2017,200, 230— 236
[14]	Jiang Z. Y., Zhang X. H., Yuan Z. M., Chen J. C., Huang B. B., Dionysiou D. D., Yang G. H., Chem. Eng. J., 2018,348, 592— 598
[15]	Yang G. H., Miao W. K., Yuan Z. M., Jiang Z. Y., Jiang Z. Y., Huang B. B., Wang P., Chen J. C., Appl. Catal. B: Environ., 2018,237, 302— 308
[16]	Jiang Z. Y., Liang X. Z., Zheng H. L., Liu Y. Y., Wang Z. Y., Wang P., Zhang X. Y., Qin X. Y., Dai Y., Whangbo M. H., Huang B. B., Appl. Catal. B: Environ., 2017,219, 209— 215
[17]	Senthilraja A., Subash B., Krishnakumar B., Rajamanickam D., Swaminathan M., Shanthi M., . Mat. Sci. Semicon Proc., 2014,22, 83— 91
[18]	Liang J., He X., Dong H. L., Liu H. R., Zhang H., Xu B. S., Chem. J. Chinese Universities, 2014,35(3), 455— 460 doi: 10.7503/cjcu20130983
	( 梁建, 何霞, 董海亮, 刘海瑞, 张华, 许并社 . 高等学校化学学报, 2014,35(3), 455— 460) doi: 10.7503/cjcu20130983
[19]	Jiang B. J., Wang P. F., Hou Z. W., Qiao Y. J., Fu H. G., Chem. J. Chinese Universities, 2012,33(11), 2544— 2548 doi: 10.7503/cjcu20120052
	( 蒋保江, 王鹏飞, 侯宗伟, 乔英杰, 付宏刚 . 高等学校化学学报, 2012,33(11), 2544— 2548) doi: 10.7503/cjcu20120052
[20]	Greene L. E., Law M., Goldberger J., Kim F., Johnson J. C., Zhang Y. F., Saykally R. J., Yang P. D., Angew. Chem. Int. Ed., 2003,42(26), 3031— 3034
[21]	Zhang Q., Deneau C. S., Zhou X., Gao G., Adv. Mater., 2009,21(41), 4087— 4108
[22]	Hamrouni A., Moussa N., Paola A. D., Parrino F., Houas A., Palmisano L., Appl. Catal. B Environ., 2014,154/155, 379— 385
[23]	Leonard K. C., Nam K. M., Lee H. C., Kang S. H., Park H. S., Bard A. J., J. Phys. Chem. C, 2013,117, 15901— 15910
[24]	Yuan K. P., Cao Q., Li X. Y., Chen H. Y., Deng Y. H., Wang Y. Y., Luo W., Lu H. L., Zhang D. W., Nano Energy, 2017,41, 543— 551

三维多孔锌钨氧化物异质结的制备、组分调控与光催化性能

Controllable Preparation and Photocatalytic Properties of Three-dimensional Porous Zinc-tungsten Oxide Heterojunctions ^†

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三维多孔锌钨氧化物异质结的制备、组分调控与光催化性能

Controllable Preparation and Photocatalytic Properties of Three-dimensional Porous Zinc-tungsten Oxide Heterojunctions †

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Controllable Preparation and Photocatalytic Properties of Three-dimensional Porous Zinc-tungsten Oxide Heterojunctions ^†