静电纺丝纳米纤维基超级电容器电极材料的研究进展

doi:10.7503/cjcu20180195

摘要/Abstract

摘要：

静电纺丝纳米纤维具有比表面积大、孔隙率高及密度低等优势, 是电化学储能材料的理想候选者之一. 本文综述了近年来静电纺丝碳纳米纤维、金属氧化物/硫化物/氮化物、导电聚合物及其复合材料在超级电容器领域的研究及应用进展, 探讨了材料组成、结构与电化学电容性能之间的关系, 并对静电纺丝纳米纤维基电极材料的发展前景进行了展望. 这将为新型高性能超级电容器电极材料的结构设计与可控制备提供新思路.

关键词: 静电纺丝, 纳米纤维, 超级电容器, 电极材料

Abstract:

Electrospun nanofibers are regarded as ideal candidates for energy storage materials due to their large specific surface area, high porosity, low density and other merits. In this review, we have presented the recent application progress of the electrospun carbon nanofibers, metal oxides/sulfides/nitrides, conducting polymers and their composites in supercapacitor electrodes. In addition, the relationship between the composition, structure and electrochemical performance was discussed in detail. Finally, the prospects for the development of the electrospun nanofiber-based electrode materials are highlighted. It is expected that this review will stimulate ideas and inspiration for the architecture design and controllable preparation of high-performance supercapacitor electrode materials.

Key words: Electrospinning, Nanofiber, Supercapacitor, Electrode material

中图分类号:

O631

TrendMD:

乜广弟, 朱云, 田地, 王策. 静电纺丝纳米纤维基超级电容器电极材料的研究进展. 高等学校化学学报, 2018, 39(7): 1349.

NIE Guangdi, ZHU Yun, TIAN Di, WANG Ce. Research Progress in the Electrospun Nanofiber-based Supercapacitor Electrode Materials^†. Chem. J. Chinese Universities, 2018, 39(7): 1349.

图/表 6

Fig.2 Schematic illustration of the gradient electrospinning and controlled pyrolysis process(A), TEM image of Co3O4 mesoporous nanotubes(B), CV curves measured at scan rate from 20 mV/s to 1000 mV/s(C), specific capacitance as a function of scan rates(D) and long-term cycling performance of Co3O4 mesoporous nanotubes at 10 V/s(E)[52]^1. Distribution of different-molecular-weight PVA in the radial direction of composite nanofibors; 2. PVA and inorganic materials moving towards the higher-molecular-weight PVA with the temperature rising slowly; 3. the preliminary pyrohysed PVA and inorganic materials converge together in the tube walls; 4. formation of mesoporous nanotubes in different gas atmospheres.^Copyright 2015, Springer Nature.

Fig.3 Schematic illustration of the preparation process of MxCo3-xS4 nanotubes with electrospun PAN nanofibers as soft templates(A), TEM images of MnCo2S4 nanotubes(B) and electrochemical performance of MnCo2S4(a) and NiCo2S4(b) nanotubes, CV curves obtained at a scan rate of 2 mV/s(C), galvanostatic charge-discharge profiles tested at a current density of 5 A/g(D), specific capacitance at different current densities(E) and cycling stability(F)[65]^Ⅰ Growth progress of M-Co shell layer on PAN nanofiber; Ⅱ solution sulfidation progress; Ⅲ removal progress of template using DMF solvent.^Copyright 2015, John Wiley and Sons.

Fig.4 Schematic illustration of the preparation process(A), SEM image of hollow PANi nanofibers(B), CV curves measured at different scan rates(C) and specific capacitance as a function of current density(D)[77]^Copyright 2013, American Chemical Society.

Fig.6 SEM image(MnO2 mass loading: 0.95 mg/cm2)(A, B) and galvanostatic charge-discharge profiles measured at a current density of 0.5 A/g of the core-shell MnO2/C nanofibers with two different diameters(C, D)[83]^(A) Mn-0.95/C-250; (B) Mn-0.95/C-650; (C) Mn/C-250; (D) Mn/C-650.^Copyright 2017, Royal Society of Chemistry.

参考文献 132

[1]	Deng Y. F., Xie Y., Zou K. X., Ji X. L., J. Mater. Chem. A, 2016, 4(4), 1144—1173
[2]	Dong L., Chen Z. X., Yang D., Lu H. B., RSC Adv., 2013, 3(44), 21183—21191
[3]	Li X., Wei B. Q., Nano Energy, 2013, 2(2), 159—173
[4]	Conway B.E., Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications, New York, Springer Science & Business Media, 1999
[5]	Augustyn V., Simon P., Dunn B., Energy Environ. Sci., 2014, 7(5), 1597—1614
[6]	Lu X. F., Wang C., Favier F., Pinna N., Adv. Energy Mater., 2017, 7(2), 1601301
[7]	Mai L. Q., Tian X. C., Xu X., Chang L., Xu L., Chem. Rev., 2014, 114(23), 11828—11862
[8]	Wei Q. L., Xiong F. Y., Tan S. S., Huang L., Lan E. H., Dunn B., Mai L. Q., Adv. Mater., 2017, 29(20), 1602300
[9]	Liu R., Duay J., Lee S. B., Chem. Commun., 2011, 47(5), 1384—1404
[10]	Li F., Li G., Chen H., Jia J. Q., Dong F., Hu Y. B., Shang Z. G., Zhang Y. X., J. Power Sources, 2015, 296, 86—91
[11]	Lu X. F., Chen X. Y., Zhou W., Tong Y. X., Li G. R., ACS Appl. Mater. Interfaces, 2015, 7(27), 14843—14850
[12]	Liu Y. C., Zhang N., Yu C. M., Jiao L. F., Chen J., Nano Lett., 2016, 16(5), 3321—3328
[13]	Liu C. K., Lai K., Liu W., Yao M., Sun R. J., Polym. Int., 2010, 58(12), 1341—1349
[14]	Inagaki M., Yang Y., Kang F. Y., Adv. Mater., 2012, 24(19), 2547—2566
[15]	Mao X. W., Hatton T. A., Rutledge G. C., Curr. Org. Chem., 2013, 17(13), 1390—1401
[16]	Wang J. G., Yang Y., Huang Z. H., Kang F. Y., J. Mater. Chem., 2012, 22(33), 16943—16949
[17]	Kim C., Yang K. S., Kojima M., Yoshida K., Kim Y. J., Kim Y. A., Endo M., Adv. Funct. Mater., 2006, 16(18), 2393—2397
[18]	Zhang B., Xu Z. L., He Y. B., Abouali S., Garakani M. A., Heidari E. K., Kang F. Y., Kim J. K., Nano Energy, 2014, 4(3), 88—96
[19]	Abouali S., Garakani M. A., Zhang B., Luo H., Xu Z. L., Huang J. Q., Huang J. Q., Kim J. K., J. Mater. Chem. A, 2014, 2(40), 16939—16944
[20]	Liu T. Y., Zhang F., Song Y., Li Y., J. Mater. Chem. A, 2017, 5(34), 17705—17733
[21]	Liu Y., Zhou J. Y., Chen L. L., Zhang P., Fu W. B., Zhao H., Ma Y. F., Pan X. J., Zhang Z. X., Han W. H., Xie E. Q., ACS Appl. Mater. Interfaces, 2015, 7(42), 23515—23520
[22]	Kim C., Ngoc B. T. N., Yang K. S., Kojima M., Kim Y. A., Kim Y. J., Endo M., Yang S. C., Adv. Mater., 2007, 19(17), 2341—2346
[23]	Lee D., Jung J. Y., Jung M. J., Lee Y. S., Chem. Eng. J., 2015, 263, 62—70
[24]	Chen L. F., Lu Y., Yu L., Lou X. W., Energy Environ. Sci., 2017, 10(8), 1777—1783
[25]	Abeykoon N. C., Bonso J. S., Ferraris J. P., RSC Adv., 2015, 5(26), 19865—19873
[26]	Ju Y. W., Park S. H., Jung H. R., Lee W. J., J. Electrochem. Soc., 2009, 156(6), A489—A494
[27]	Le T. H., Ying Y., Huang Z. H., Kang F. Y., J. Power Sources, 2015, 278, 683—692
[28]	An G. H., Koo B. R., Ahn H. J., Phys. Chem. Chem. Phys., 2016, 18(9), 6587—6594
[29]	Kim C., Yang K. S., Appl. Phys. Lett., 2003, 83(6), 1216—1218
[30]	Ma C., Li Y. J., Shi J. L., Song Y., Liu L., Chem. Eng. J., 2014, 249, 216—225
[31]	Zhi M. J., Liu S. H., Hong Z. L., Wu N. Q., RSC Adv., 2014, 4(82), 43619—43623
[32]	Kou T. Y., Yao B., Liu T. Y., Li Y., J. Mater. Chem. A, 2017, 5(33), 17151—17173
[33]	Li X. L., Zhao Y. J., Bai Y., Zhao X. Y., Wang R. H., Huang Y. C., Liang Q. H., Huang Z. H., Electrochim. Acta, 2017, 230, 445—453
[34]	Tian X. D., Zhao N., Song Y., Wang K., Xu D. F., Li X., Guo Q. G., Liu L., Electrochim. Acta, 2015, 185, 40—51
[35]	Jung K. H., Deng W. J., Jr D. W. S., Ferraris J. W., Electrochem. Commun., 2012, 23, 149—152
[36]	Tran C., Kalra V., J. Power Sources, 2013, 235, 289—296
[37]	Liang Q. H., Ye L., Xu Q., Huang Z. H., Kang F. Y., Yang Q. H., , 2015, 94, 342—348
[38]	Lai C. C., Lo C. T., RSC Adv., 2015, 5(49), 38868—38872
[39]	Hyun T. S., Tuller H. L., Youn D. Y., Kim H. G., Kim I. D., J. Mater. Chem., 2010, 20(41), 9172—9179
[40]	Wang J. G., Kang F. Y., Wei B. Q., Prog. Mater. Sci., 2015, 74, 51—124
[41]	Bhagwan J., Sahoo A., Yadav K. L., Sharma Y., Electrochim. Acta, 2015, 174, 992—1001
[42]	Lee E., Lee T., Kim B. S., J. Power Sources, 2014, 255, 335—340
[43]	Lee J. H., Yang T. Y., Kang H. Y., Nam D. H., Kim N. R., Lee Y. Y., Lee S. H., Joo Y. C., J. Mater. Chem. A, 2014, 2(20), 7197—7204
[44]	Xu K. B., Li S. J., Yang J. M., Hu J. Q., J. Colloid. Interf. Sci., 2018, 513, 448—454
[45]	Yan Y., Li B., Guo W., Pang H., Xue H. G., J. Power Sources, 2016, 329, 148—169
[46]	Liu M. S., Su B., Tang X., Jiang X. C., Yu A. B., Adv. Energy Mater., 2017, 7(23), 1700885
[47]	Wee G., Soh H. Z., Cheah Y. L., Mhaisalkar S. G., Srinivasan M., J. Mater. Chem., 2010, 20(32), 6720—6725
[48]	Lala N. L., Jose R., Yusoff M. M., Ramakrishna S., J. Nanopart. Res., 2012, 14(11), 1201
[49]	Ren B., Fan M. Q., Liu Q., Wang J., Song D. L., Bai X. F., Electrochim. Acta, 2013, 92, 197—204
[50]	Kundu M., Liu L. F., Mater. Lett., 2015, 144, 114—118
[51]	Ren B., Fan M. Q., Wang J., Jing X. Y., Bai X. F., J. Electrochem. Soc., 2013, 160(9), E79—E83
[52]	Niu C. J., Meng J. S., Wang X. P., Han C. H., Yan M. Y., Zhao K. N., Xu X. M., Ren W. H., Zhao Y. L., Xu L., Zhang Q. J., Zhao D. Y., Mai L. Q., Nat. Commun., 2015, 6, 7402
[53]	Qu Q. T., Yang S. B., Feng X. L., Adv. Mater., 2011, 23(46), 5574—5580
[54]	Xia Q. Y., Xu M., Xia H., Xie J. P., Chem. Nano Mat., 2016, 2(7), 588—600
[55]	Binitha G., Soumya M. S., Madhavan A. A., Praveen P., Balakrishnan A., Subramanian K. R. V., Reddy M. V., Nair S. V., Nair A. S., Sivakumar N., J. Mater. Chem. A, 2013, 1(38), 11698—11704
[56]	Liu B., Tan D. S., Wang X. F., Chen D., Shen G. Z., Small, 2013, 9(11), 1998—2004
[57]	Zhou G., Zhu J., Chen Y. J., Mei L., Duan X. C., Zhang G. H., Chen L. B., Wang T. H., Lu B. A., Electrochim. Acta, 2014, 123, 450—455
[58]	Li L. L., Peng S. J., Cheah Y., Teh P., Wang J., Wee G., Ko Y., Wong C., Srinivasan M., Chem. Eur. J., 2013, 19(19), 5892—5898
[59]	Peng S. J., Li L. L., Hu Y. X., Srinivasan M., Cheng F. Y., Chen J., Ramakrishna S., ACS Nano, 2015, 9(2), 1945—1954
[60]	Bhagwan J., Sivasankaran V., Yadav K. L., Sharma Y., J. Power Sources, 2016, 327, 29—37
[61]	Wang Q. F., Chen D., Zhang D. H., RSC Adv., 2015, 5(117), 96448—96454
[62]	Alkhalaf S., Ranaweera C. K., Kahol P. K., Siam K., Adhikari H., Mishra S. R., Perez F., Gupta B. K., Ramasamy K., Gupta R. K., J. Alloy. Compd., 2017, 692, 59—66
[63]	Yu X. Y., Yu L., Lou X. W., Adv. Energy Mater., 2016, 6(3), 1501333
[64]	Zhu H., Zhang J. F., Yanzhang R. P., Du M. L., Wang Q. F., Gao G. H., Wu J. D., Wu G. M., Zhang M., Liu B., Yao J. M., Zhang X. W., Adv. Mater., 2015, 27(32), 4752—4759
[65]	Chen Y. M., Li Z., Lou X. W., Angew. Chem. Int. Ed., 2015, 54(36), 10521—10524
[66]	Choi D., Kumta P. N., J. Electrochem. Soc., 2006, 153(12), A2298—A2303
[67]	Liu T. C., Pell W. G., Conway B. E., J. Electrochem. Soc., 1998, 145(6), 1882—1888
[68]	Zhao J. X., Liu B., Xu S., Yang J., Lu Y., J. Alloy. Compd., 2015, 651, 785—792
[69]	Xu Y. L., Wang J., Shen L. F., Dou H., Zhang X. G., Electrochim. Acta, 2015, 173, 680—686
[70]	Wang J. F., Wang J. R., Kong Z., Lv K. L., Teng C., Zhu Y., Adv. Mater., 2017, 29(45), 1703044
[71]	Meng Q. F., Cai K. F., Chen Y. X., Chen L. D., Nano Energy, 2017, 36, 268—285
[72]	Wang K., Wu H. P., Meng Y. N., Wei Z. X., Small, 2014, 10(1), 14—31
[73]	Ni W., Cheng J. L., Li X. D., Gu G. F., Huang L., Guan Q., Yuan D. M., Wang B., RSC Adv., 2015, 5(12), 9221—9227
[74]	Simotwo S. K., Delre C., Kalra V., ACS Appl. Mater. Interfaces, 2016, 8(33), 21261—21269
[75]	Lee K. M., Kim M., Lee E., Baeck S. H., Sang E. S., Electrochim. Acta, 2016, 213, 124—131
[76]	Miao F. J., Shao C. L., Li X. H., Lu N., Wang K. X., Zhang X., Liu Y. C., Electrochim. Acta, 2015, 176, 293—300
[77]	Miao Y. E., Fan W., Chen D., Liu T. X., ACS Appl. Mater. Interfaces, 2013, 5(10), 4423—4428
[78]	Laforgue A., J. Power Sources, 2011, 196(1), 559—564
[79]	Dong Q., Wang G., Hu H., Yang J., Qian B. Q., Ling Z., Qiu J. S., J. Power Sources, 2013, 243, 350—353
[80]	An G. H., Ahn H. J., Hong W. K., J. Power Sources, 2015, 274, 536—541
[81]	Abouali S., Garakani M. A., Zhang B., Xu Z. L., Heidari E. K., Huang J. Q., Huang J. Q., Kim J. K., ACS Appl. Mater. Interfaces, 2015, 7(24), 13503—13511
[82]	Zhou D., Lin H. M., Zhang F., Niu H., Cui L. R., Wang Q., Qu F. Y., Electrochim. Acta, 2015, 161, 427—435
[83]	Saito Y., Meguro M., Ashizawa M., Waki K., Yuksel R., Unalan H. E., Matsumoto H., RSC Adv., 2017, 7(20), 12351—12358
[84]	Samuel E., Joshi B., Jo H. S., Kim Y. I., An S., Swihart M. T., Yun J. M., Kim K. H., Yoon S. S., Chem. Eng. J., 2017, 328, 776—784
[85]	Ge J. L., Qu Y. S., Cao L. T., Wang F., Dou L. Y., Yu J. Y., Ding B., J. Mater. Chem. A, 2016, 4(20), 7795—7804
[86]	Lei D. Y., Li X. D., Seo M. K., Khil M. S., Kim H. Y., Kim B. S., Polymer, 2017, 132, 31—40
[87]	Wang F. F., Sun S. G., Xu Y. Q., Wang T., Yu R. J., Li H. J., Sci. Rep., 2017, 7, 4707
[88]	Lai F. L., Huang Y. P., Miao Y. E., Liu T. X., Electrochim. Acta, 2015, 174, 456—463
[89]	Liu Y., Zhou J. Y., Fu W. B., Zhang P., Pan X. J., Xie E. Q., , 2017, 114, 187—197
[90]	Xu J. L., Zhang L., Xu G. C., Sun Z. P., Zhang C., Ma X., Qi C. L., Zhang L., Jia D. Z., Appl. Surf. Sci., 2018, 434, 112—119
[91]	Kumuthini R., Ramachandran R., Therese H. A., Wang F., J. Alloy. Compd., 2017, 705, 624—630
[92]	Liu Y. K., Jiang G. H., Sun S. Q., Xu B., Zhou J. Y., Zhang Y., Yao J. M., J. Alloy. Compd., 2018, 731, 560—568
[93]	Wu Y. G., Ran F., J. Power Sources, 2017, 344, 1—10
[94]	Ren Y. Q., Dai J., Pang B., Liu X., Yu J., Electrochim. Acta, 2015, 176, 402—409
[95]	Miao F. J., Shao C. L., Li X. H., Lu N., Wang K. X., Zhang X., Liu Y. C., Energy, 2016, 95, 233—241
[96]	He S. J., Hu X. W., Chen S. L., Hu H., Hanif M., Hou H. Q., J. Mater. Chem., 2012, 22(11), 5114—5120
[97]	Yan X. B., Tai Z. X., Chen J. T., Xue Q. J., Nanoscale, 2011, 3(1), 212—216
[98]	Kim S. Y., Kim B. H., J. Power Sources, 2016, 328, 219—227
[99]	Jia J. F., Luo F. Y., Gao C. J., Suo C., Wang X. C., Song H. Z., Hu X., Ceram. Int., 2014, 40(5), 6973—6977
[100]	Zhu J., Xu Z., Lu B. A., Nano Energy, 2014, 7, 114—123
[101]	Nie G. D., Li S. K., Lu X. F., Wang C., Chem. J. Chinese Universities, 2013, 34(1), 15—29
	(乜广弟,力尚昆,卢晓峰,王策.高等学校化学学报, 2013, 34(1), 15—29
[102]	Li D., Xia Y. N., Adv. Mater., 2004, 16(14), 1151—1170
[103]	Greiner A., Wendroff J. H., Angew. Chem. Int. Ed., 2007, 46(30), 5670—5703
[104]	Nie G. D., Lu X. F., Lei J. Y., Jiang Z. Q., Wang C., J. Mater. Chem. A, 2014, 2(37), 15495—15501
[105]	Nie G. D., Lu X. F., Chi M. Q., Zhu Y., Yang Z. Z., Song N., Wang C., Electrochim. Acta, 2017, 231, 36—43
[106]	Radhamani A. V., Shareef K. M., Rao M. S. R., ACS Appl. Mater. Interfaces, 2016, 8(44), 30531—30542
[107]	Gong D. C., Zhu J., Lu B. A., RSC Adv., 2016, 6(54), 49173—49178
[108]	Jiang P. C., Wang Q., Dai J. F., Li W. X., Wei Z. Q., Mater. Lett., 2017, 188, 69—72
[109]	Harilal M., Vidyadharan B., Misnon I. I., Anilkumar G. M., Lowe A., Ismail J., Yusoff M. M., Jose R., ACS Appl. Mater. Interfaces, 2017, 9(12), 10730—10742
[110]	Vijayan B. L., Krishnan S. G., Zain N. K. M., Harilal M., Yar A., Misnon I. I., Dennis J. O., Yusoff M. M., Jose R., Chem. Eng. J., 2017, 327, 962—972
[111]	Niu H., Zhou D., Yang X., Li X., Wang Q., Qu F. Y., J. Mater. Chem. A, 2015, 3(36), 18413—18421
[112]	Xu K. B., Li S. J., Yang J. M., Xu H. Y., Hu J. Q., J. Alloy. Compd., 2016, 678, 120—125
[113]	Agyemang F. O., Kim H., Mater. Sci. Eng. B, 2016, 211, 141—148
[114]	Huang Y. P., Miao Y. E., Lu H. Y., Liu T. X., Chem. Eur. J., 2015, 21(28), 10100—10108
[115]	Lu X. Y., Shen C., Zhang Z. Y., Barrios E., Zhai L., ACS Appl. Mater. Interfaces, 2018, 10(4), 4041—4049
[116]	Tong L. Y., Liu J., Boyer S. M., Sonnenberg L. A., Fox M. T., Ji D. S., Feng J., Bernier W. E., Jones Jr. W. E., Electrochim. Acta, 2017, 224, 133—141
[117]	Zhou X. H., Shang C. Q., Gu L., Dong S. M., Chen X., Han P. X., Li L. F., Yao J. H., Liu Z. H., Xu H. X., Zhu Y. W., Cui G. L., ACS Appl. Mater. Interfaces, 2011, 3(8), 3058—3063
[118]	Zhou J. Y., Chen J. Y., Han S., Zhao H., Bai J. L., Yang Z. Y., Mu X. M., Liu Y., BianD. M., Sun G. Z., Zhang Z. X., Pan X. J., Xie E. Q., , 2017, 111, 502—512
[119]	Agyemang F. O., Tomboc G. M., Kwofie S., Kim H., Electrochim. Acta, 2018, 259, 1110—1119
[120]	Miao F. J., Shao C. L., Li X. H., Wang K. X., Lu N., Liu Y. C., ACS Sustainable Chem. Eng., 2016, 4(3), 1689—1696
[121]	Iqbal N., Wang X. F., Babar A. A., Zainab G., Yu J. Y., Ding B., Sci. Rep., 2017, 7, 15153
[122]	Zhang J., Su L. J., Ma L., Zhao D. Y., Qin C. L., Jin Z., Zhao K., J. Electroanal. Chem., 2017, 790, 40—49
[123]	Zhou G. Y., Xiong T. R., He S. J., Li Y. H., Zhu Y. M., Hou H. Q., J. Power Sources, 2016, 317, 57—64
[124]	Chen L., Zhu J. H., Chem. Commun., 2014, 50(60), 8253—8256
[125]	Lai F. L., Miao Y. E, Huang Y. P., Chung T. S., Liu T. X., J. Phys. Chem. C, 2015, 119(24), 13442—13450
[126]	Iqbal N., Wang X. F., Babar A. A., Yu J. Y., Ding B., J. Colloid Interf. Sci., 2016, 476, 87—93
[127]	Lee D. G., Kim Y. A., Kim B. H., , 2016, 107, 783—791
[128]	Chen L., Chen L. N., Ai Q., Li D. P., Si P. C., Feng J. K., Zhang L., Li Y. H., Lou J., Ci L. J., Chem. Eng. J., 2018, 334, 184—190
[129]	Shi M. J., Zhao L. P., Song X. F., Liu J., Zhang P., Gao L., ACS Appl. Mater. Interfaces, 2016, 8(47), 32460—32467
[130]	Huang J., Wei J. C., Xu Y. Z., Xiao Y. B., Chen Y. W., J. Mater. Chem. A, 2017, 5(44), 23349—23360
[131]	Liu Y. K., Jiang G. H., Sun S. Q., Xu B., Zhou J. Y., Zhang Y., Yao J. M., J. Electroanal. Chem., 2017, 804, 212—219
[132]	Nie G. D., Lu X. F., Chi M. Q., Gao M., Wang C., J. Colloid Interf. Sci., 2018, 509, 235—244