晶态纳米纤维素的多色圆偏振荧光性能

doi:10.7503/cjcu20190635

摘要/Abstract

摘要：

基于晶态纳米纤维素禁带效应的圆偏振荧光能力, 分别采用混合悬浮液法及多层膜叠加法拓宽了晶态纳米纤维素膜的禁带, 使其禁带覆盖可见光范围, 通过掺杂多色荧光体, 该膜可以将自发辐射转换为高强度、右旋、多色的圆偏振荧光信号.

关键词: 晶态纳米纤维素, 手性向列有序性, 光子禁带, 圆偏振荧光, 多色

Abstract:

Multi-color circularly polarized luminescence with high luminescence dissymmetry(g_lum) factors is key in photonic technologies. Leveraging on the intrinsic circular polarization ability of cellulose nanocrystals(CNC), we demonstrate that mixing of CNC suspensions, which are supersonically treated for a different period of time, provides an effective approach to produce freestanding CNC films with a broad photonic bandgap that can effectively transform spontaneous emissions to multicolor right-handed CPL signals with high g_lum. We also show that lamination of multiple CNC-CdSe/ZnS films affords an easy approach to broaden photonic bangdap and ability to produce multicolor circularly polarized luminescence with high g_lum.

Key words: Cellulose nanocrystal, Chiral nematic order, Photonic bandgap, Circularly polarized luminescence, Multi-color

中图分类号:

O636.1
O644

TrendMD:

赵子一,郑洪芝,徐雁. 晶态纳米纤维素的多色圆偏振荧光性能. 高等学校化学学报, 2020, 41(5): 1120.

ZHAO Ziyi,ZHENG Hongzhi,XU Yan. Multi-color Circularly Polarized Luminescence Properties of Cellulose Nanocrystal ^†. Chem. J. Chinese Universities, 2020, 41(5): 1120.

图/表 7

Scheme 1 Synthetic route of CNCvisible-CdSe/ZnS CNCvisible-CdSe/ZnS was prepared by evaporation-induced self-assembly(EISA) from suspensions prepared by mixing of two CNC-CdSe/ZnS suspensions that were supersonically treated for 5 and 15 s, respectively. Five types of CdSe/ZnS were added to the suspension mixture.

Fig.1 Photograph of CNCvisible-CdSe/ZnS taken on a black background showing reflected colors of turquoise blue, yellow and maroon(A), POM image of CNCvisible-CdSe/ZnS showing birefringence patterns with fingerprint textures and domains of different orientations(B), SEM images showing left-handed helicoids and microgaps between anisotropic domains(C) and domains of different orientation and polydispersed helical pitches(D)

Fig.2 UV-Vis transmission spectrum of CNCvisible-CdSe/ZnS(a) showing a broad selective reflection bank across entire visible spectrum and photoemission spectra of the dilute solutions of CdSe/ZnS442(b), CdSe/ZnS502(c), CdSe/ZnS542(d), CdSe/ZnS598(e) and CdSe/ZnS644(f)

Fig.3 CD spectrum of CNCvisible-CdSe/ZnS showing a positive broad band across entire visible spectrum

Fig.4 CPL spectrum of CNCvisible-CdSe/ZnS showing multi-color R-CPL with varied glum

Fig.5 UV-Vis spectra(A), CD spectra(B) and corresponding SEM image(C) of five CNCPBG-CdSe/ZnSPL films a. CNC443-CdSe/ZnS; b. CNC502-CdSe/ZnS; c. CNC542-CdSe/ZnS; d. CNC598-CdSe/ZnS; e. CNC644-CdSe/ZnS.

Fig.6 Schematics(A), UV-Vis(B), CD(C) and CPL(D, E) spectra of multilayer film (B) UV-Vis transmission spectrum of multilayer film(a), photoemission spectra of the dilute solutions of CdSe/ZnS442(b), CdSe/ZnS502(c), CdSe/ZnS542(d), CdSe/ZnS598(e) and CdSe/ZnS644(f).

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