高等学校化学学报 ›› 1988, Vol. 9 ›› Issue (10): 1074-1076.

• 论文 • 上一篇    下一篇

胺烷基二茂铁衍生物研究(Ⅱ)——(N、N-二乙基)胺甲基二茂铁钯配合物与烯烃的反应

张伦1, 向进福1, 王双力1, 王冀英2   

  1. 1. 武汉大学化学系;
    2. 陕西师范大学化学系
  • 收稿日期:1987-04-02 出版日期:1988-10-24 发布日期:1988-10-24
  • 通讯作者: 张伦

Studies on Aminoalkylferrocene Derivatives (Ⅱ)--The Reactions for Palladium complex of N,N- Diefhylaminomethylferrocene with Olefins

Zhang Lun1, Xiang Jinfu1, Wang Shuangli1, Wang Jiying2   

  1. 1. Chemistry Department, Wuhan University, Wuhan;
    2. Chemistry Department, Shaanxi Normal University, Xi'an
  • Received:1987-04-02 Online:1988-10-24 Published:1988-10-24

摘要: 本文报道了(N,N-二乙基)胺甲基二茂铁钯配合物的合成及其与烯烃的反应,以及(N,N-二乙基)胺甲基二茂铁(Ⅰ)、钯配合物(Ⅱ)和反应产物的波谱性质。

关键词: 胺烷基二茂铁, 钯配合物, 烯烃

Abstract: In this communication we report on the synthesis of the palladium complex of N,N-diethylaminomethylferrocene, di-μ-chloro-bis(2-(diethylaminometh-yl)ferrocenyl)dipalladium, and its reactions with styrene, methyl propenate, and 2-ferrocenylpfopene. The palladium complex and all the reaction products, which have been identified by elemental analyses, IR, 1H NMRspectra, are 1,2-disubsti-tuted ferrocene.

Key words: Aminoalkylferrocene, Palladium complex, Olefin