高等学校化学学报

高等学校化学学报 ›› 1988, Vol. 9 ›› Issue (7): 647.

• 论文 •    下一篇

N,N′-乙二水杨酰胺合铜(Ⅱ)酸根的Cu(Ⅱ)-Co(Ⅱ)配合物的合成与磁性

廖代正   

  1. 南开大学化学系
  • 收稿日期:1986-12-13 出版日期:1988-07-24 发布日期:1988-07-24

Synthesis and Magnetism of Copper(Ⅱ)-Cobalt(Ⅱ)Complexes with N,N'-Ethylenedisalicylamidatocuprate(Ⅱ)

Liao Daizheng   

  1. Department of Chemistry Nankai University, Tianjin
  • Received:1986-12-13 Online:1988-07-24 Published:1988-07-24

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摘要： 本文报道了2个新的Cu(Ⅱ)-Co(Ⅱ)双核配合物的制备。经元素分析和红外、电子光谱以及变温磁化率的测定,研究了配合物的某些性质。

关键词: 双核配合物, Cu(Ⅱ)-Co(Ⅱ), 磁性

Abstract: New binuclear complexes of type [Cu(samen)Co(L)]2 were synthesized,where samen 4- denotes N,N'-ethylenedisalicylamidate anion and Ldenotes 2,2'-dipyridyl or 1,10-phenanthrolirie. Based on IR, elemental analyses and electronic spectra, the complexes are proposed to consist of a Cu(Ⅱ) in a distorted planar environment and Cod) in a distorted octahedron. The magnetisms of the Cu(Ⅱ)-Co(Ⅱ) complexes were well interpreted in terms of the susceptibility equation based on Heisenberg model.

Key words: Binuclear complex, Copper (Ⅱ)-cobalt (Ⅱ), Magnetism

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