高等学校化学学报 ›› 2011, Vol. 32 ›› Issue (8): 1733.

• 研究论文 • 上一篇    下一篇

色素的纳米纸色谱分离分析

周聪, 袁平, 陈波, 姚守拙   

  1. 湖南师范大学化学生物学及中药分析教育部重点实验室, 长沙 410081
  • 收稿日期:2010-09-27 修回日期:2010-11-23 出版日期:2011-08-10 发布日期:2011-07-19
  • 通讯作者: 陈波 E-mail:dr-chenpo@vip.sina.com
  • 基金资助:

    国家自然科学基金(批准号: 20927005, 20875028, 21005027)、国家"八六三"计划项目(批准号: 2010AA023001)、湖南省应用基础计划项目(批准号: 2010TT1001)和湖南省研究生创新课题(批准号: CX2010B221)资助.

Analysis of Pigments by Nano\|particle Modified Paper Chromatography

ZHOU Cong, YUAN Ping, CHEN Bo*, YAO Shou-Zhuo   

  1. Key Laboratory of Chemical Biology & Traditional Chinese Medicine Research, Ministry of Education, Hunan Normal University, Changsha 410081, China
  • Received:2010-09-27 Revised:2010-11-23 Online:2011-08-10 Published:2011-07-19
  • Contact: CHEN Bo E-mail:dr-chenpo@vip.sina.com
  • Supported by:

    国家自然科学基金(批准号: 20927005, 20875028, 21005027)、国家"八六三"计划项目(批准号: 2010AA023001)、湖南省应用基础计划项目(批准号: 2010TT1001)和湖南省研究生创新课题(批准号: CX2010B221)资助.

摘要: 本文采用SiO2纳米粒子结合硅烷化处理对滤纸进行改性,以罗丹明B、苏丹红I、苏丹红IV为模型化合物,考察改性滤纸在分离特性上的差异。经过对不同粒径纳米粒子、不同硅烷化试剂、不同展开剂极性进行比较、优化后,发现经过改性纳米粒子修饰后的滤纸与原滤纸相比,在同等展开条件下分离色素的效果得到明显的改善,纳米粒子越小,烷基碳链越长,硅烷化越完全,色素斑点越集中,分离效果越好,其保留行为与反相液相色谱相似。

关键词: 纳米粒子, 纸色谱, 硅烷化改性, 色素

Abstract: Rhodamine B, Sudan I, and Sudan IV were used as model compounds to investigate the different separation characteristics of filter paper which had been modified by silica nanoparticles and silylation reagents. The effects of different nanoparticles size, carbon chains length of silylation reagents and treated methods on the separation characteristics of modified filter paper has been studied. The results showed that, the paper modified by smaller silica nanoparticles size, longer carbon chains length, owned better separation performance. The modified filter paper has the similar retention behavior with reversed-phase column chromatography.

Key words: Nanoparticle, Paper chromatography, Silylation modification, Pigment

TrendMD: