新型共价键连的富勒烯-卟啉化合物的合成与表征

高等学校化学学报 ›› 2005, Vol. 26 ›› Issue (7): 1202.

新型共价键连的富勒烯-卟啉化合物的合成与表征

杨森根, 刘见永, 吴振奕, 田玲, 凡素华, 詹梦熊

厦门大学化学系, 厦门361005

收稿日期:2004-11-10 出版日期:2005-07-10 发布日期:2005-07-10
通讯作者: 杨森根(1946年出生),男,副教授,从事配位化学研究.E-mail:sgyang@jingxian.xmu.edu.cn E-mail:sgyang@jingxian.xmu.edu.cn
基金资助:
福建省自然科学基金(批准号:E0410001);厦门大学自选课题基金(批准号:0040-Y07008)资助

Synthesis and Characterization of Novel Covalently Linked Fullerene-porphyrin Compouds

YANG Sen-Gen, LIU Jian-Yong, WU Zhen-Yi, TIAN Ling, FAN Su-Hua, ZHAN Meng-Xiong

Depart_ment of Chemistry, Xiamen University, Xiamen 361005, China

Received:2004-11-10 Online:2005-07-10 Published:2005-07-10

摘要/Abstract

摘要： 为了构造一个具有有效电荷转移的给-受体体系,通过1,3-偶极加成反应,由5-[2-'(4″-醛基苯氧丙氧苯基)]-10,15,20-三苯基卟啉(H₂P-CHO)、肌氨酸和C₆₀首次合成了一种新的以共价键相连的富勒烯-卟啉配体(H₂P-C₆₀),同时用该配体制备了其锌配合物(ZnP-C₆₀),并用红外光谱、元素分析、电子光谱、核磁共振氢谱和质谱等方法进行了表征.

关键词: 富勒烯, 富勒烯吡咯烷, 卟啉, 金属卟啉

Abstract: In order to construct a donor-acceptor system with efficient electron transfer, a novel covalently linked fullerene-porphyrin ligand(H₂P-C₆₀) was synthesized by 1,3-dipolar cycloaddition reaction of C₆₀, sarcosine and H₂P-CHO, and it's zinc derivative was prepared by metalation of H₂P-C₆₀ and zinc acetate. The two new fullerene-porphyrin compounds were characterized by means of elemental analysis, IR, electronic spectra, ESI-MS and ¹H NMR.They are also predicted to have good optical and electrical properties.

Key words: Fullerene, Fulleropyrrolidine, Porphyrin, Metal Porphyrin

中图分类号:

O613.71

TrendMD:

杨森根, 刘见永, 吴振奕, 田玲, 凡素华, 詹梦熊. 新型共价键连的富勒烯-卟啉化合物的合成与表征. 高等学校化学学报, 2005, 26(7): 1202.

YANG Sen-Gen, LIU Jian-Yong, WU Zhen-Yi, TIAN Ling, FAN Su-Hua, ZHAN Meng-Xiong. Synthesis and Characterization of Novel Covalently Linked Fullerene-porphyrin Compouds. Chem. J. Chinese Universities, 2005, 26(7): 1202.

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