阵列聚合物纳米柱膜的超疏水性研究

高等学校化学学报 ›› 2004, Vol. 25 ›› Issue (7): 1375.

阵列聚合物纳米柱膜的超疏水性研究

金美花^1,2, 冯琳², 封心建², 翟锦², 江雷², 白玉白¹, 李铁津¹

1. 吉林大学化学学院, 长春 130023;
2. 中国科学院化学研究所分子科学中心, 北京 100080

收稿日期:2003-11-04 出版日期:2004-07-24 发布日期:2004-07-24
通讯作者: 江雷(1965年出生),男,博士,研究员,博士生导师,从事功能纳米界面材料科技研究.E-mail:jianglei@iccas.ac.cn E-mail:jianglei@iccas.ac.cn
基金资助:
国家自然科学基金(批准号:20374054)资助

Super-hydrophobicity of Aligned Polymer Nanopole Films

JIN Mei-Hua^1,2, FENG Lin², FENG Xin-Jian², ZHAI Jin², JIANG Lei², BAI Yu-Bai¹, LI Tie-Jin¹

1. College of Chemistry, Jilin University, Changchun 130023, China;
2. Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China

Received:2003-11-04 Online:2004-07-24 Published:2004-07-24

摘要/Abstract

摘要： 浸润性(又称润湿性,Wettability)是固体表面的一个重要特征,它主要由表面化学组成和表面的几何结构两方面控制^[1～5].近年来,超疏水性固体表面由于在防雪、防污染、抗氧化以及防止电流等方面都有非常广阔的应用前景,引起了人们的极大关注[6～11].

关键词: 超疏水, 阵列聚合物, 纳米柱

Abstract: Wettability is a very important property governed by both the chemical composition and the geometrical structure of solid surfaces. Super-hydrophobic surface[with water contact angle(CA) larger than 150°] have been extensively investigated due to their importance for industrial applications. In the present study, we describe a rather simple method for synthesizing separated alignments of polymer nanopole films, which has super-hydrophobic property with water a contact angle as high as 152.0°. Nanostructures that induce the large fraction of air on the surface cause this unique property.

Key words: Super-hydrophobicity, Aligned polymer, Nanopole

中图分类号:

O631

TrendMD:

金美花, 冯琳, 封心建, 翟锦, 江雷, 白玉白, 李铁津. 阵列聚合物纳米柱膜的超疏水性研究. 高等学校化学学报, 2004, 25(7): 1375.

JIN Mei-Hua, FENG Lin, FENG Xin-Jian, ZHAI Jin, JIANG Lei, BAI Yu-Bai, LI Tie-Jin. Super-hydrophobicity of Aligned Polymer Nanopole Films. Chem. J. Chinese Universities, 2004, 25(7): 1375.

参考文献

[1] Nish ino T.,Megu ro M.,Nakam ae K.et al..Langm u ir[J],1999,15:4 321—4 323 [2] Youngb lood J.P.,McCarthy T.J..Macrom o lecu les[J],1999,32:6 800—6806 [3] Nakajim a A.,Fu jish im a A.,Hash im o to K.et al..Adv.Mater.[J],1999,11:1 365—1 368 [4] LI Huan-Jun(李欢军),WANG Xian-Bao(王贤宝),JIANG Lei(江　雷)et al..Chem.J.Ch inese Un iversities(高等学校化学学报)[J],2001,22(5):759—761 [5] LI Shu-Hong(李书宏),FENG Lin(冯　琳),LI Huan-Jun(李欢军)et al..Chem.J.Ch inese Un iversities(高等学校化学学报)[J],2003,24(2):340—342 [6] Wenzel R.N..Ind.Eng.Chem.[J],1936,28:988—994 [7] Cassie A.B.D.,Bax ter S..Tran s.Faraday Soc.[J],1944,40:546—551 [8] Sw ain P.S.,Lipow sky R..Langmuir[J],1998,14:6 772—6 780 [9] Wolan sky G.,Marm u r A..Langmuir[J],1998,14:5 292—5 297 [10] Chen W.,Fadeev A.Y.,Hsieh M.C.et al..Langm u ir[J],1999,15:3 395—3 399 [11] Oner D.,McCarthy T.J..Langm u ir[J],2000,16:7 777—7 782 [12] Jiang L.,Wang R.,Yang B.et al..Pu re App l.Chem.[J],2000,72:73—81 [13] Wang R.,Hash im o to K.,Fu jish im a A.et al..Natu re[J],1997,388:434—435 [14] Fu jish im a A.,Hash im o to K.,Watanabe T..TiO 2 Pho tocatalyst,Fundam en tals and App lication[M],Tokyo:BKC,1999 [15] Ph llip Ball.Natu re[J],1999,400:507—509 [16] Feng L.,Li S.H.,Jiang L.et al..Angew.Chem.In t.Ed.[J],2002,41:1 221—1 223 [17] Sh ibu ich i S.,Onda T.,Satoh N.et al..J.Phys.Chem.[J],1996,100:19 512—19 517 [18] Tadanaga K.,Katata N.,Minam i T..J.Am.Cerm.Soc.[J],1997,80:3 213—3 216 [19] Tadanaga T.,Mo rinaga J.,Matsuda A.et al..Chem.Mater.[J],2000,12:590—592 [20] Li S.H.,Li H.J.,Jiang L.et al..J.Phys.Chem.B[J],2002,106:9 274—9 276 [21] Feng L.,Li S.H.,Jiang L.et al..Adv.Mater.[J],2002,14:1 857—1 860 [22] Erb il H.Y.,Dem irel A.L.,Avci Y.et al..Science[J],2003,299:1 377—1 380 [23] Li H.J.,Wang X.,Song Y.L.et al..Angew.Chem.In t.Ed.[J],2001,40:1 743—1 745