高等学校化学学报 ›› 2004, Vol. 25 ›› Issue (12): 2359.

• 研究论文 • 上一篇    下一篇

一种新型磺化聚醚醚酮的合成、表征和性能

刘晨光, 那辉, 赵成吉, 吴忠文   

  1. 吉林大学化学学院麦克德尔米德实验室, 长春130021
  • 收稿日期:2003-12-29 出版日期:2004-12-24 发布日期:2004-12-24
  • 基金资助:

    国家自然科学基金(批准号:20320120169);吉林省重大科技发展项目(批准号:20020646)资助

Synthesis, Characterization and Properties of the Novel Sulfonated Poly(ether ether ketone)s

LIU Chen-Guang, NA Hui, ZHAO Cheng-Ji, WU Zhong-Wen   

  1. Alan G MacDiarmid Institiute, College of Chemistry, Jilin University, Changchun 130021, China
  • Received:2003-12-29 Online:2004-12-24 Published:2004-12-24

摘要: 以特丁基对苯二酚、3,3′-二磺酸钠基-4,4′-二氟二苯酮和4,4′-二氟二苯酮为单体,制备了具有高磺化度的聚醚醚酮.该系列聚合物可溶,并具有良好的成膜性.对聚合物及其膜的一些性能进行了研究.

关键词: 聚醚醚酮, 特丁基对苯二酚, 磺化,

Abstract: A series of novel sulfonated poly(aryl ether ketone)s based on tert-butylhydroquinone were synthesized via aromatic nucleophilic substitution reaction with the intrinsic viscosities above 0.77. The samples were characterized by FTIR and DSC method. All the polymers are readily soluble cast into tough membranes. The solubility and other properties of the polymer membranes were studies in the article.

Key words: Poly(ether ether ketone)s, tert-Butylhydroquinone, Sulfonation, Membrane

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