高等学校化学学报 ›› 2002, Vol. 23 ›› Issue (1): 22.

• 研究简报 • 上一篇    下一篇

8-羟基喹啉镍配合物[Ni2(HQ)3Q3]ClO4的晶体结构

张明杰2, 黄岩谊1, 黄春辉1, 徐光宪1   

  1. 1. 北京大学稀土材料化学及应用国家重点实验室, 北京大学化学与分子工程学院, 北京 100871;
    2. 中国科学院兰州化学物理研究所, 兰州 730000
  • 收稿日期:2001-01-08 出版日期:2002-01-24 发布日期:2002-01-24
  • 通讯作者: 张明杰(1959年出生),男,博士,教授,从事有机配合物化学研究.E-mail:chem@tju.edu.cn E-mail:chem@tju.edu.cn

Crystal Structure of Tri(8-quinolinol) Nickel Coordination Compound [Ni2(HQ)3Q3] ClO4

ZHANG Ming-Jie2, HUANG Yan-Yi1, HUANG Chun-Hui1, XU Guang-Xian1   

  1. 1. State Key Laboratory of Rare Earth Materials Chemistryand Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China;
    2. Departmentof Chemistry, Tianjin University, Tianjin 300072, China
  • Received:2001-01-08 Online:2002-01-24 Published:2002-01-24

关键词: 8-羟基喹啉, 镍, 配位化合物, 晶体结构

Abstract: A tri(8-quinolinol)nickel coordination compound, [Ni2(HQ)3Q3] ClO4, was synthesized and its crystal structure was determined by X-ray diffraction. The crystal structure indicated a space group of P21/c with a =1.6138(1) nm, b =1.5900(1) nm, c =1.9399(1) nm, β =94.663(2)°, V = 4.9612(6) nm3 and Z =4. Three strong hydrogen bonds were found in each unique unit between two tri(8-quinolinol) nickel fragments.

Key words: 8-Quinolinol, Nickel, Coordination compound, Crystal structure

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