高等学校化学学报

高等学校化学学报 ›› 2001, Vol. 22 ›› Issue (11): 1951.

• 研究简报 • 上一篇    

不饱和环缩醛与苯乙烯的原子转移自由基共聚合反应

袁金颖1,2, 徐旭荣1, 潘才元2   

  1. 1. 北京大学化学与分子工程学院高分子科学与工程系, 北京 100871;
    2. 中国科学技术大学高分子科学与工程系, 合肥 230026
  • 收稿日期:2000-11-28 出版日期:2001-11-24 发布日期:2001-11-24
  • 通讯作者: 袁金颖(1965年出生),女,博士,主要从事开环聚合、活性聚合及拉胀聚合物研究.E-mail:jyyuan@chem.pku.edu.cn E-mail:jyyuan@chem.pku.edu.cn
  • 基金资助:

    国家自然科学基金(批准号:29774027)资助

Atom Transfer Radical Copolymerization of Unsaturated Cyclic Acetal with Styrene

YUAN Jin-Ying1,2, XU Xu-Rong1, PAN Cai-Yuan2   

  1. 1. Department of Polymer Scienceand Engineering, Collegeof Chemistry and Molecular Engineering, Peking University, Beijing 100871, China;
    2. Deptartment of Polymer Scienceand Engineering, University of Scienceand Technology of China, Hefei 230026, China
  • Received:2000-11-28 Online:2001-11-24 Published:2001-11-24

PDF (PC)

被引次数

1

关键词: 原子转移自由基聚合, 自由基共聚合, 开环聚合, 分子量分布

Abstract: This paper is the first report on the atom transfer radical copolymerization of unsaturated cyclic acetal, 4,7-dimethyl-2-methylene-1,3-dioxepane(DMMDO) and styrene(St) in the presence of α bromobutyrate as the initiator and CuBr/2,2'-bipyridine as the catalyst/ligand at 110 ℃ was investigated. Both DMMDO and St components could be found in main chains of the obtained polymer, and the copolymer had a narrow molecular weight distribution. DMMDO component in the copolymer contained both addition and ring opening units, thus the ester bond was introduced into the main chain, and the copolymer could be chemically degradable and biologically degradable.

Key words: Atom transfer radical polymerization, Free radical copolymerization, Ring opening polymerization, Molecular weight distribution

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